Preparation, Crystal Structure and Caracterization of Inorganic-Organic Hybrid Perovskite [NH3-(CH2)10-NH3] ZnCl4
| hal.structure.identifier | Laboratoire de Physique des Matériaux et Modélisation des Systèmes [Meknès] [LP2MS] | |
| dc.contributor.author | ELMEBROUKI, Keltoum | |
| hal.structure.identifier | Ecole Supérieur de Technologie [Meknès] | |
| dc.contributor.author | KHECHOUBI, El Mostafa | |
| hal.structure.identifier | Laboratoire de Physique des Matériaux et Modélisation des Systèmes [Meknès] [LP2MS] | |
| dc.contributor.author | KAÏBA, Abdellah | |
| hal.structure.identifier | Laboratoire de Physique des Matériaux et Modélisation des Systèmes [Meknès] [LP2MS] | |
| dc.contributor.author | BELAARAJ, Abdesselam | |
| hal.structure.identifier | Laboratoire Ondes et Matière d'Aquitaine [LOMA] | |
| dc.contributor.author | MONDIEIG, Denise | |
| hal.structure.identifier | Laboratoire Ondes et Matière d'Aquitaine [LOMA] | |
| dc.contributor.author | NÉGRIER, Philippe | |
| dc.date.issued | 2013-05-01 | |
| dc.identifier.issn | 2226-5724 | |
| dc.description.abstractEn | A new perovskite like system [NH3-(CH2)10-NH3] ZnCl4, has been synthesized and characterized by single crystal X-ray diffraction, thermal analysis and infrared spectroscopic study. This compound crystallize in a triclinic space group P-1, with the unit cell parameters a=7.294(1), b=10.058(9) Å, c=12.812(1) Å, α = 90, 89(2), β = 101, 21(1), γ = 92, 40(3) and Z=2. The final R factor is 0,082. The structure of this compound might be described as layered with two parallel anionic and cationic layers. The first layer is composed by isolated distorted tetrahedral (ZnCl4)2- and the second layer of [NH3-(CH2)x-NH3]2+. Network hydrogen - bonding assures the cohesion between these layers and stabilizes the crystal. The structure shows the existence of a conformational disorder of the organic chains between " trans " and " twisted " states. The thermal analysis by DSC shows that the 2C10ZnCl4 perovskite presents reversible phase transition. | |
| dc.language.iso | en | |
| dc.publisher | AESS Publications | |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc/ | |
| dc.subject.en | Perovskite structure | |
| dc.subject.en | Molecular composite | |
| dc.subject.en | X-ray diffraction | |
| dc.subject.en | Crystal structure | |
| dc.subject.en | phase transitions in layered systems | |
| dc.title.en | Preparation, Crystal Structure and Caracterization of Inorganic-Organic Hybrid Perovskite [NH3-(CH2)10-NH3] ZnCl4 | |
| dc.type | Article de revue | |
| dc.subject.hal | Chimie/Cristallographie | |
| bordeaux.journal | Journal of Asian Scientific Research | |
| bordeaux.page | 454-461 | |
| bordeaux.volume | 3 | |
| bordeaux.issue | 5 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00843371 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00843371v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Journal%20of%20Asian%20Scientific%20Research&rft.date=2013-05-01&rft.volume=3&rft.issue=5&rft.spage=454-461&rft.epage=454-461&rft.eissn=2226-5724&rft.issn=2226-5724&rft.au=ELMEBROUKI,%20Keltoum&KHECHOUBI,%20El%20Mostafa&KA%C3%8FBA,%20Abdellah&BELAARAJ,%20Abdesselam&MONDIEIG,%20Denise&rft.genre=article |
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