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hal.structure.identifierLaboratoire Ondes et Matière d'Aquitaine [LOMA]
dc.contributor.authorWÜRGER, Alois
dc.date.created2013-08-12
dc.date.issued2014-01-01
dc.identifier.issn0953-8984
dc.description.abstractEnWe study thermal diffusion in binary mixtures in the framework of non-equilibrium thermodynamics. Our formal result displays the role of partial enthalpies hi and Onsager's generalized mobilities Ai. The ratio A1/A2 provides a measure for the irreversible character of thermal diffusion. Comparison with experimental data on benzene, cyclohexane, toluene and n-alkanes shows that irreversibility is essential for thermal diffusion, and in particular for the isotope effect.
dc.language.isoen
dc.publisherIOP Publishing
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/
dc.title.enThermodiffusion in binary liquids: the role of irreversibility
dc.typeArticle de revue
dc.identifier.doi10.1088/0953-8984/26/3/035105
dc.subject.halPhysique [physics]/Matière Condensée [cond-mat]/Matière Molle [cond-mat.soft]
dc.identifier.arxiv1401.7537
bordeaux.journalJournal of Physics: Condensed Matter
bordeaux.page035105 (1-5)
bordeaux.volume26
bordeaux.issue3
bordeaux.peerReviewedoui
hal.identifierhal-00917630
hal.version1
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00917630v1
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