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Metal-to-Metal Electron Transfer in Co/Fe Prussian Blue Molecular Analogues: The Ultimate Miniaturization.

hal.structure.identifierCentre de recherches Paul Pascal [CRPP]
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorKOUMOUSI, Evangelia S.
hal.structure.identifierCentre de recherches Paul Pascal [CRPP]
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorJEON, Ie-Rang
hal.structure.identifierCollege of Chemistry, Key Laboratory of Pesticide and Chemical Biology
dc.contributor.authorGAO, Qian
hal.structure.identifierCentre de recherches Paul Pascal [CRPP]
dc.contributor.authorDECHAMBENOIT, Pierre
hal.structure.identifierCentre de recherches Paul Pascal [CRPP]
dc.contributor.authorWOODRUFF, Daniel N.
hal.structure.identifierCentre de recherches Paul Pascal [CRPP]
dc.contributor.authorMERZEAU, Pascal
hal.structure.identifierCentre de recherches Paul Pascal [CRPP]
dc.contributor.authorBUISSON, Lionel
hal.structure.identifierCollege of Chemistry, Key Laboratory of Pesticide and Chemical Biology
dc.contributor.authorJIA, Xiaolu
hal.structure.identifierCollege of Chemistry, Key Laboratory of Pesticide and Chemical Biology
dc.contributor.authorLI, Dongfeng
hal.structure.identifierInstitut de Chimie Moléculaire et des Matériaux d'Orsay [ICMMO]
dc.contributor.authorVOLATRON, Florence
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorMATHONIÈRE, Corine
hal.structure.identifierCentre de recherches Paul Pascal [CRPP]
dc.contributor.authorCLÉRAC, Rodolphe
dc.date.issued2014
dc.identifier.issn0002-7863
dc.description.abstractEnCo/Fe Prussian Blue analogues are known to display both thermally and light induced electron transfer attributed to the switching between diamagnetic {Fe(II)LS(μ-CN)Co(III)LS} and paramagnetic {Fe(III)LS(μ-CN)Co(II)HS} pairs (LS = low spin; HS = high spin). In this work, a dinuclear cyanido-bridged Co/Fe complex, the smallest {Fe(μ-CN)Co} moiety at the origin of the remarkable physical properties of these systems, has been designed by a rational building-block approach. Combined structural, spectroscopic, magnetic and photomagnetic studies reveal that a metal-to-metal electron transfer that can be triggered in solid state by light, temperature and solvent contents, is observed for the first time in a dinuclear complex.
dc.description.sponsorshipSynthèse et étude de chaines aimant photocommutables - ANR-12-PDOC-0038
dc.language.isoen
dc.publisherAmerican Chemical Society
dc.title.enMetal-to-Metal Electron Transfer in Co/Fe Prussian Blue Molecular Analogues: The Ultimate Miniaturization.
dc.typeArticle de revue
dc.identifier.doi10.1021/ja508094h
dc.subject.halChimie/Matériaux
bordeaux.journalJournal of the American Chemical Society
bordeaux.page15461-15464
bordeaux.volume136
bordeaux.issue44
bordeaux.peerReviewedoui
hal.identifierhal-01088567
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-01088567v1
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