Bifunctional materials based on the photochromic cation [RuNO(NH3)5]3+ with paramagnetic metal complex anions
| hal.structure.identifier | Institute of Problems of Chemical Physics | |
| dc.contributor.author | KUSHCH, Lyudmila A. | |
| hal.structure.identifier | Institute of Problems of Chemical Physics | |
| dc.contributor.author | KUROCHKINA, Lyudmila S. | |
| hal.structure.identifier | Institute of Problems of Chemical Physics | |
| dc.contributor.author | YAGUBSKII, Eduard B. | |
| hal.structure.identifier | Institute of Problems of Chemical Physics | |
| dc.contributor.author | SHILOV, Gennadii V. | |
| hal.structure.identifier | Institute of Problems of Chemical Physics | |
| dc.contributor.author | ALDOSHIN, Sergei M. | |
| hal.structure.identifier | Institute of Inorganic Chemistry | |
| dc.contributor.author | EMELYANOV, Vyacheslav A. | |
| hal.structure.identifier | M.N. Mikheev Institute of Metal Physics [IMP] | |
| dc.contributor.author | SHVACHKO, Yurii N. | |
| hal.structure.identifier | A. V. Shubnikov Institute of Crystallography [IC RAS] | |
| dc.contributor.author | MIRONOV, Vladimir S. | |
| hal.structure.identifier | Institut für Mineralogie | |
| dc.contributor.author | SCHANIEL, Dominik | |
| hal.structure.identifier | Institut für Mineralogie | |
| dc.contributor.author | WOIKE, Theo | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | CARBONERA, Chiara | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | MATHONIÈRE, Corine | |
| dc.date.issued | 2006 | |
| dc.identifier.issn | 1434-1948 | |
| dc.description.abstractEn | The synthesis of a series of compounds containing the photochromic mononitrosyl cation, [RuNO(NH3)5]3+ and metal complex paramagnetic anions [M(CN)6]3- [M = Cr (1), Fe(2)], [M(ox)3]3- [M = Cr(3), Fe(4)] and [CrNO(CN)5]3- (5) is reported. The crystal structures of the salts 1 and 3 are discussed. In contrast to 1 and 3 which exhibit reversible photochromic properties, illumination of 2 and 4 results in an irreversible photochemical reaction and compound 5 is not photochromic at all. The magnetic properties of 1 and 3 have been investigated and complex 1 shows a weak reversible increase in the value of MT under light irradiation at low temperature. | |
| dc.language.iso | en | |
| dc.publisher | Wiley-VCH Verlag | |
| dc.subject.en | Photochromism | |
| dc.subject.en | Magnetic properties | |
| dc.subject.en | Mononitrosyl ruthenium complexes | |
| dc.subject.en | Paramagnetic metal complexes | |
| dc.title.en | Bifunctional materials based on the photochromic cation [RuNO(NH3)5]3+ with paramagnetic metal complex anions | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1002/ejic.200600271 | |
| dc.subject.hal | Chimie/Matériaux | |
| bordeaux.journal | European Journal of Inorganic Chemistry | |
| bordeaux.page | p. 4074-4085 | |
| bordeaux.volume | n° 20 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00110630 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Non spécifiée | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00110630v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=European%20Journal%20of%20Inorganic%20Chemistry&rft.date=2006&rft.volume=n%C2%B0%2020&rft.spage=p.%204074-4085&rft.epage=p.%204074-4085&rft.eissn=1434-1948&rft.issn=1434-1948&rft.au=KUSHCH,%20Lyudmila%20A.&KUROCHKINA,%20Lyudmila%20S.&YAGUBSKII,%20Eduard%20B.&SHILOV,%20Gennadii%20V.&ALDOSHIN,%20Sergei%20M.&rft.genre=article |
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