Mechanochromic luminescence of copper iodide clusters.
hal.structure.identifier | Laboratoire de physique de la matière condensée [LPMC] | |
dc.contributor.author | BENITO, Quentin | |
hal.structure.identifier | Laboratoire de physique de la matière condensée [LPMC] | |
dc.contributor.author | MAURIN, Isabelle | |
hal.structure.identifier | Laboratoire Hétéroéléments et Coordination [DCPH] | |
dc.contributor.author | CHEISSON, Thibaut | |
hal.structure.identifier | Laboratoire Hétéroéléments et Coordination [DCPH] | |
dc.contributor.author | NOCTON, Gregory | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | FARGUES, Alexandre | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | GARCIA, Alain | |
hal.structure.identifier | Institut Lavoisier de Versailles [ILV] | |
dc.contributor.author | MARTINEAU, Charlotte | |
hal.structure.identifier | Laboratoire de physique de la matière condensée [LPMC] | |
dc.contributor.author | GACOIN, Thierry | |
hal.structure.identifier | Laboratoire de physique de la matière condensée [LPMC] | |
dc.contributor.author | BOILOT, Jean-Pierre | |
hal.structure.identifier | Laboratoire de physique de la matière condensée [LPMC] | |
dc.contributor.author | PERRUCHAS, Sandrine | |
dc.date.issued | 2015 | |
dc.identifier.issn | 0947-6539 | |
dc.description.abstractEn | Luminescent mechanochromic materials are particularly appealing for the development of stimuli-responsive materials. Establishing the mechanism responsible for the mechanochromism is always an issue owing to the difficulty in characterizing the ground phase. Herein, the study of real crystalline polymorphs of a mechanochromic and thermochromic luminescent copper iodide cluster permits us to clearly establish the mechanism involved. The local disruption of the crystal packing induces changes in the cluster geometry and in particular the modification of the cuprophilic interactions, which consequently modify the emissive states. This study constitutes a step further toward the understanding of the mechanism involved in the mechanochromic luminescent properties of multimetallic coordination complexes. | |
dc.language.iso | en | |
dc.publisher | Wiley-VCH Verlag | |
dc.title.en | Mechanochromic luminescence of copper iodide clusters. | |
dc.type | Article de revue | |
dc.identifier.doi | 10.1002/chem.201500251 | |
dc.subject.hal | Chimie/Matériaux | |
bordeaux.journal | Chemistry - A European Journal | |
bordeaux.page | 5892-5897 | |
bordeaux.volume | 21 | |
bordeaux.issue | 15 | |
bordeaux.peerReviewed | oui | |
hal.identifier | hal-01137300 | |
hal.version | 1 | |
hal.popular | non | |
hal.audience | Internationale | |
hal.origin.link | https://hal.archives-ouvertes.fr//hal-01137300v1 | |
bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Chemistry%20-%20A%20European%20Journal&rft.date=2015&rft.volume=21&rft.issue=15&rft.spage=5892-5897&rft.epage=5892-5897&rft.eissn=0947-6539&rft.issn=0947-6539&rft.au=BENITO,%20Quentin&MAURIN,%20Isabelle&CHEISSON,%20Thibaut&NOCTON,%20Gregory&FARGUES,%20Alexandre&rft.genre=article |
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