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hal.structure.identifierLaboratoire des oxydes et fluorures [LdOF ]
dc.contributor.authorLEGEIN, Christophe
hal.structure.identifierCentre de recherches sur les matériaux à haute température [CRMHT]
hal.structure.identifierFédération RMN du Solide à Hauts Champs [FRMN-SHC]
dc.contributor.authorFAYON, Franck
hal.structure.identifierLaboratoire des oxydes et fluorures [LdOF ]
dc.contributor.authorMARTINEAU, Charlotte
hal.structure.identifierLaboratoire des oxydes et fluorures [LdOF ]
dc.contributor.authorBODY, M.
hal.structure.identifierLaboratoire des oxydes et fluorures [LdOF ]
dc.contributor.authorBUZARÉ, Jean-Yves
hal.structure.identifierCentre de recherches sur les matériaux à haute température [CRMHT]
hal.structure.identifierFédération RMN du Solide à Hauts Champs [FRMN-SHC]
dc.contributor.authorMASSIOT, Dominique
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorDURAND, Etienne
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorTRESSAUD, Alain
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorDEMOURGUES, Alain
hal.structure.identifierLaboratoire des oxydes et fluorures [LdOF ]
dc.contributor.authorPERRON, O.
hal.structure.identifierLaboratoire des oxydes et fluorures [LdOF ]
dc.contributor.authorBOULARD, B.
dc.date.issued2006
dc.identifier.issn0020-1669
dc.description.abstractEnHigh magnetic field and high spinning frequency one- and two-dimensional one-pulse MAS 19F NMR spectra of -ZrF4 and CeF4 were recorded and reconstructed allowing the accurate determination of the 19F chemical shift tensor parameters for the seven different crystallographic fluorine sites of each compound. The attributions of the NMR resonances are performed using the superposition model for 19F isotropic chemical shift calculation initially proposed by Bureau et al. (Bureau, B.; Silly, G.; Emery, J.; Buzaré, J.-Y. Chem. Phys. 1999, 249, 85-104). A satisfactory reliability is reached with a root-mean-square (rms) deviation between calculated and measured isotropic chemical shift values equal to 1.5 and 3.5 ppm for -ZrF4 and CeF4, respectively.
dc.language.isoen
dc.publisherAmerican Chemical Society
dc.title.en19F High Magnetic Field NMR Study of β-ZrF4 and CeF4: from Spectra Reconstruction to Correlation between Fluorine Sites and 19F Isotropic Chemical Shifts
dc.typeArticle de revue
dc.identifier.doi10.1021/ic061339a
dc.subject.halChimie/Matériaux
bordeaux.journalInorganic Chemistry
bordeaux.page10636-10641
bordeaux.volume45
bordeaux.issue26
bordeaux.peerReviewedoui
hal.identifierhal-00115872
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00115872v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Inorganic%20Chemistry&rft.date=2006&rft.volume=45&rft.issue=26&rft.spage=10636-10641&rft.epage=10636-10641&rft.eissn=0020-1669&rft.issn=0020-1669&rft.au=LEGEIN,%20Christophe&FAYON,%20Franck&MARTINEAU,%20Charlotte&BODY,%20M.&BUZAR%C3%89,%20Jean-Yves&rft.genre=article


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