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hal.structure.identifierDepartment of Chemistry, Indian Institute of Technology
dc.contributor.authorGHOSH, Aloke Kumar
dc.contributor.authorMAHAPATRA, Tufan Singha
hal.structure.identifierCentre de recherches Paul Pascal [CRPP]
dc.contributor.authorCLÉRAC, Rodolphe
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorMATHONIÈRE, Corine
hal.structure.identifierDipartemento di Science Chimiche e Farmaceutiche
dc.contributor.authorBERTOLASI, Valerio
hal.structure.identifierDepartment of Chemistry, Indian Institute of Technology
dc.contributor.authorRAY, Debashis
dc.date.issued2015-05-18
dc.identifier.issn0020-1669
dc.description.abstractEnA [NiII4] staircase complex was serendipitously prepared from the reaction of the binucleating Schiff base proligand 2,6-bis[[(3-hydroxypropyl)imino]-methyl]-4-methylphenol (H3L2) and 3,5-dimethylpyrazole (Me2pzH) with nickel(II) nitrate in a reaction at room temperature, initially aimed to yield a dinuclear complex. From a room temperature metal ion/ligand reaction, the proligand H3L2 in situ transformed to modified formsHL32− and HL42−, allowing the [Ni4] formation. Variable temperature magnetic behavior of a [Ni4] complex reveals antiferromagnetic interactions with stabilization of a diamagnetic ground state (ST = 0).
dc.language.isoen
dc.publisherAmerican Chemical Society
dc.title.enDirect C−N Coupling in an in Situ Ligand Transformation and the Self-Assembly of a Tetrametallic [NiII4] Staircase
dc.typeArticle de revue
dc.identifier.doi10.1021/acs.inorgchem.5b00411
dc.subject.halChimie/Matériaux
bordeaux.journalInorganic Chemistry
bordeaux.page5136-5138
bordeaux.volume54
bordeaux.issue11
bordeaux.peerReviewedoui
hal.identifierhal-01161910
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-01161910v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Inorganic%20Chemistry&rft.date=2015-05-18&rft.volume=54&rft.issue=11&rft.spage=5136-5138&rft.epage=5136-5138&rft.eissn=0020-1669&rft.issn=0020-1669&rft.au=GHOSH,%20Aloke%20Kumar&MAHAPATRA,%20Tufan%20Singha&CL%C3%89RAC,%20Rodolphe&MATHONI%C3%88RE,%20Corine&BERTOLASI,%20Valerio&rft.genre=article


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