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hal.structure.identifierInstitut für Anorganische und Analytische Chemie
dc.contributor.authorPÖTTGEN, Rainer
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorCHEVALIER, Bernard
dc.date.issued2015
dc.description.abstractEnThe equiatomic CeXX′ phases (X and X′ = elements of the 3rd, 4th, or 5th main group) extend the large series of CeTX intermetallics (T = electron-rich transition metal). These phases crystallize with simple structure types, i.e. ZrNiAl, TiNiSi, CeScSi, α-ThSi2, AlB2, and GdSi2. In contrast to the CeTX intermetallics one observes pronounced solid solutions for the CeXX′ phases. The main influence on the magnetic ground states results from theabsence of d electrons. All known CeXX′ phases show exclusively trivalent cerium and antiferro- or ferromagnetic ordering at low temperatures. The crystal chemical details and some structure-property relationships are reviewed.
dc.language.isoen
dc.subject.encerium compounds
dc.subject.encrystal structure
dc.subject.enintermetallics
dc.subject.enmagnetic properties
dc.subject.enstructure–property relationship
dc.title.enEquiatomic cerium intermetallics CeXX' with two p elements
dc.typeArticle de revue
dc.identifier.doi10.1515/znb-2015-0109
dc.subject.halChimie/Matériaux
bordeaux.journalZeitschrift für Naturforschung, B: Chemical Sciences
bordeaux.page695-704
bordeaux.volume70
bordeaux.issue10
bordeaux.peerReviewedoui
hal.identifierhal-01220443
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-01220443v1
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