Insertion of a [FeII(pyimH)3]2+ [pyimH = 2-(1H-Imidazol-2-yl)pyridine] Spin-Crossover Complex Inside a Ferromagnetic Lattice Based on a Chiral 3D Bimetallic Oxalate Network
hal.structure.identifier | Instituto de Ciencia Molecular [ICMol] | |
dc.contributor.author | LÓPEZ-JORDÀ, Maurici | |
hal.structure.identifier | Instituto de Ciencia Molecular [ICMol] | |
dc.contributor.author | GIMÉNEZ-MARQUÉS, Mónica | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | DESPLANCHES, Cédric | |
hal.structure.identifier | Instituto de Ciencia Molecular [ICMol] | |
dc.contributor.author | MÍNGUEZ ESPALLARGAS, Guillermo | |
hal.structure.identifier | Instituto de Ciencia Molecular [ICMol] | |
dc.contributor.author | CLEMENTE-LEÓN, Miguel | |
dc.date.issued | 2016 | |
dc.identifier.issn | 1434-1948 | |
dc.description.abstractEn | The insertion of the [FeII(pyimH)3]2+ [pyimH = 2-(1H-imidazol-2-yl)pyridine] spin-crossover complex into a ferromagnetic bimetallic oxalate network affords the hybrid compound [FeII(pyimH)3][MnIICrIII(ox)3]2·X (ox = C2O42–). This spin-crossover complex templates the growth of crystals formed by a chiral 3D oxalate network. The magnetic properties of this hybrid magnet show the coexistence of long-range ferromagnetic ordering at 4.5 K and a spin crossover of the intercalated [FeII(pyimH)3]2+ complex above 250 K. The compound presents a light-induced excited spin-state trapping (LIESST) effect below 60 K although with limited photoconversion (less than 8 %). | |
dc.language.iso | en | |
dc.publisher | Wiley-VCH Verlag | |
dc.subject.en | Spin crossover | |
dc.subject.en | Magnetic properties | |
dc.subject.en | Chirality | |
dc.subject.en | Iron | |
dc.subject.en | Oxalates | |
dc.title.en | Insertion of a [FeII(pyimH)3]2+ [pyimH = 2-(1H-Imidazol-2-yl)pyridine] Spin-Crossover Complex Inside a Ferromagnetic Lattice Based on a Chiral 3D Bimetallic Oxalate Network | |
dc.type | Article de revue | |
dc.identifier.doi | 10.1002/ejic.201500790 | |
dc.subject.hal | Chimie/Matériaux | |
bordeaux.journal | European Journal of Inorganic Chemistry | |
bordeaux.page | 2187–2192 | |
bordeaux.issue | 13-14 | |
bordeaux.peerReviewed | oui | |
hal.identifier | hal-01315419 | |
hal.version | 1 | |
hal.popular | non | |
hal.audience | Internationale | |
hal.origin.link | https://hal.archives-ouvertes.fr//hal-01315419v1 | |
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