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Revisited crystal symmetry of the high-spin form of the iron (II) spin-crossover complex dicyano[2,13-dimethyl-6,9-dioxa-3,12,18-triazabicyclo[12.3.1]octadeca-1(18),2,12,14,16-pentaene]iron(II) monohydrate

hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorGUIONNEAU, Philippe
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorCOSTA, José Sánchez
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorLÉTARD, Jean-François
dc.date.issued2004
dc.identifier.issn0108-2701
dc.description.abstractEnThe title iron(II) complex, [Fe(CN)2(C15H23N3O2)]·H2O, is of interest to the spin-crossover community because of its unusual temperature-dependent magnetic behaviour as well as its relatively high relaxation temperature for the light-induced spin-crossover phenomenon. Structural modifications are strongly suspected to cause the unusual thermal spin-crossover features. Recently, the high-spin crystal structure has been reported but with an inadequate space group...
dc.language.isoen
dc.publisherInternational Union of Crystallography
dc.subject.en[Fe(CN)2(C15H23N3O2)]·H2O
dc.subject.enCrystal structure
dc.subject.enIron(II)
dc.subject.enSpin crossover
dc.title.enRevisited crystal symmetry of the high-spin form of the iron (II) spin-crossover complex dicyano[2,13-dimethyl-6,9-dioxa-3,12,18-triazabicyclo[12.3.1]octadeca-1(18),2,12,14,16-pentaene]iron(II) monohydrate
dc.typeArticle de revue
dc.identifier.doi10.1107/S010827010402445X
dc.subject.halChimie/Matériaux
bordeaux.journalActa Crystallographica Section C : Crystal Structure Communications [1968-2013]
bordeaux.pagem587-m589
bordeaux.volume60
bordeaux.peerReviewedoui
hal.identifierhal-00152881
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00152881v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Acta%20Crystallographica%20Section%20C%20:%20Crystal%20Structure%20Communications%20%5B1968-2013%5D&rft.date=2004&rft.volume=60&rft.spage=m587-m589&rft.epage=m587-m589&rft.eissn=0108-2701&rft.issn=0108-2701&rft.au=GUIONNEAU,%20Philippe&COSTA,%20Jos%C3%A9%20S%C3%A1nchez&L%C3%89TARD,%20Jean-Fran%C3%A7ois&rft.genre=article


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