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A new organic-inorganic coordination complex material (C2H5-C6H4-NH2)2ZnBr2: Growth and structural properties

hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
hal.structure.identifierLaboratoire de Physique des Matériaux et Modélisation des Systèmes [LP2MS]
dc.contributor.authorHARMOUZI, Asmaa
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorDARO, Nathalie
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorGUIONNEAU, Philippe
hal.structure.identifierLaboratoire de Physique des Matériaux et Modélisation des Systèmes [LP2MS]
dc.contributor.authorBELAARAJ, Abdesselam
hal.structure.identifierEcole Supérieur de Technologie
dc.contributor.authorKHECHOUBI, El Mostafa
dc.date.issued2017
dc.identifier.issn0022-0248
dc.description.abstractEnSingle crystals of an organic-inorganic hybrid (C2H5-C6H4-NH2)2ZnBr2 have been grown by the slow-diffusion method and characterized by Single-Crystal X-Ray Diffraction (SC-XRD) at 295 K. This compound crystallizes in the monoclinic system, with the space group C2/c and the following cell parameters: a = 32.336 (3) Å, b = 4.8539 (4) Å, c = 12.2334 (9) Å, β = 97.019 (5)°, V = 1905.7(3) Å3 and Z′ = 4. The crystal packing is based on well-ordered alternating ZnBr2 inorganic layers and C2H5-C6H4-NH2 organic layers. The crystal structure has been analyzed and discussed in terms of molecular geometry as well as intra and intermolecular interactions. Comparisons with some homologues materials of general formula (R-NH2)2ZnX2 (X = Cl, Br), (R = C2H5-C6H4, C6H5) are also done.
dc.language.isoen
dc.publisherElsevier
dc.subject.enOrganic-inorganic materials
dc.subject.enSingle-crystal
dc.subject.enCrystal structure
dc.subject.enX-ray diffraction
dc.title.enA new organic-inorganic coordination complex material (C2H5-C6H4-NH2)2ZnBr2: Growth and structural properties
dc.typeArticle de revue
dc.identifier.doi10.1016/j.jcrysgro.2017.02.013
dc.subject.halChimie/Matériaux
bordeaux.journalJournal of Crystal Growth
bordeaux.page64-70
bordeaux.volume472
bordeaux.peerReviewedoui
hal.identifierhal-01542505
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-01542505v1
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