A new organic-inorganic coordination complex material (C2H5-C6H4-NH2)2ZnBr2: Growth and structural properties
HARMOUZI, Asmaa
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
Laboratoire de Physique des Matériaux et Modélisation des Systèmes [LP2MS]
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Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
Laboratoire de Physique des Matériaux et Modélisation des Systèmes [LP2MS]
HARMOUZI, Asmaa
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
Laboratoire de Physique des Matériaux et Modélisation des Systèmes [LP2MS]
< Reduce
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
Laboratoire de Physique des Matériaux et Modélisation des Systèmes [LP2MS]
Language
en
Article de revue
This item was published in
Journal of Crystal Growth. 2017, vol. 472, p. 64-70
Elsevier
English Abstract
Single crystals of an organic-inorganic hybrid (C2H5-C6H4-NH2)2ZnBr2 have been grown by the slow-diffusion method and characterized by Single-Crystal X-Ray Diffraction (SC-XRD) at 295 K. This compound crystallizes in the ...Read more >
Single crystals of an organic-inorganic hybrid (C2H5-C6H4-NH2)2ZnBr2 have been grown by the slow-diffusion method and characterized by Single-Crystal X-Ray Diffraction (SC-XRD) at 295 K. This compound crystallizes in the monoclinic system, with the space group C2/c and the following cell parameters: a = 32.336 (3) Å, b = 4.8539 (4) Å, c = 12.2334 (9) Å, β = 97.019 (5)°, V = 1905.7(3) Å3 and Z′ = 4. The crystal packing is based on well-ordered alternating ZnBr2 inorganic layers and C2H5-C6H4-NH2 organic layers. The crystal structure has been analyzed and discussed in terms of molecular geometry as well as intra and intermolecular interactions. Comparisons with some homologues materials of general formula (R-NH2)2ZnX2 (X = Cl, Br), (R = C2H5-C6H4, C6H5) are also done.Read less <
English Keywords
Organic-inorganic materials
Single-crystal
Crystal structure
X-ray diffraction
Origin
Hal imported