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hal.structure.identifierChemical Crystallography Group, Chemistry Department
dc.contributor.authorMONEY, Victoria A.
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorCARBONERA, Chiara
hal.structure.identifierSchool of Chemistry [Leeds]
dc.contributor.authorELHAÏK, Jérôme
hal.structure.identifierSchool of Chemistry [Leeds]
dc.contributor.authorHALCROW, Malcolm A.
hal.structure.identifierChemical Crystallography Group, Chemistry Department
dc.contributor.authorHOWARD, Judith A. K.
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorLÉTARD, Jean-François
dc.date.issued2007
dc.identifier.issn0947-6539
dc.description.abstractEnhis paper describes the first material to show the well-known light-induced excited spin-state trapping (LIESST) effect, the metastable excited state of which relaxes at a temperature approaching its thermal spin-crossover. Cooling polycrystalline [FeL2][BF4]2x H2O (L=2,6-bis{3-methylpyrazol-1-yl}pyridine; x=0-1/3) at 1 K min-1 leads to a cooperative spin transition, taking place in two steps centered at 147 and 105 K, that is only 54 % complete by magnetic susceptibility...
dc.language.isoen
dc.publisherWiley-VCH Verlag
dc.subject.enCoordination chemistry
dc.subject.enIron
dc.subject.enMagnetic properties
dc.subject.enPhotomagnetism
dc.subject.enSpin crossover
dc.title.enInterplay between kinetically slow thermal spin-crossover and metastable high-spin state relaxation in an iron(II) complex with similar T1/2 and T(LIESST)
dc.typeArticle de revue
dc.identifier.doi10.1002/chem.200601312
dc.subject.halChimie/Matériaux
bordeaux.journalChemistry - A European Journal
bordeaux.page5503-5514
bordeaux.volume13
bordeaux.issue19
bordeaux.peerReviewedoui
hal.identifierhal-00160388
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00160388v1
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