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Variation of M···H–C interactions in square-planar complexes of nickel(II), palladium(II), and platinum(II) probed by luminescence spectroscopy and X-ray diffraction at variable pressure

hal.structure.identifierDépartement de chimie [UdeM-Montréal]
dc.contributor.authorPOIRIER, Stéphanie
hal.structure.identifierDépartement de chimie [UdeM-Montréal]
dc.contributor.authorLYNN, Hudson
hal.structure.identifierUniversité de Montréal [UdeM]
hal.structure.identifierDépartement de chimie [UdeM-Montréal]
dc.contributor.authorREBER, Christian
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorTAILLEUR, Élodie
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorMARCHIVIE, Mathieu
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorGUIONNEAU, Philippe
hal.structure.identifierChemistry, School of Natural and Environmental Sciences
dc.contributor.authorPROBERT, Michael
dc.date.issued2018-06-12
dc.identifier.issn0020-1669
dc.description.abstractEnLuminescence spectra of isoelectronic square-planar d8 complexes with 3d, 4d, and 5d metal centers show d–d luminescence with an energetic order different from that of the spectrochemical series, indicating that additional structural effects, such as different ligand–metal–ligand angles, are important factors. Variable-pressure luminescence spectra of square-planar nickel(II), palladium(II), and platinum(II) complexes with dimethyldithiocarbamate ({CH3}2DTC) ligands and their deuterated analogues show unexpected variations of the shifts of their maxima. High-resolution crystal structures and crystal structures at variable pressure for [Pt{(CH3)2DTC}2] indicate that intermolecular M···H–C interactions are at the origin of these different shifts.
dc.language.isoen
dc.publisherAmerican Chemical Society
dc.title.enVariation of M···H–C interactions in square-planar complexes of nickel(II), palladium(II), and platinum(II) probed by luminescence spectroscopy and X-ray diffraction at variable pressure
dc.typeArticle de revue
dc.identifier.doi10.1021/acs.inorgchem.8b00724
dc.subject.halChimie/Matériaux
bordeaux.journalInorganic Chemistry
bordeaux.page7713-7723
bordeaux.volume57
bordeaux.issue13
bordeaux.peerReviewedoui
hal.identifierhal-01833179
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-01833179v1
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