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Bis(hexafluoroacetylacetonato)manganese(II) complex of 1,1-dimethyl-2,5-bis-(3-N-tert-butyl-N-phenylaminoxyl) -3,4-diphenylsilolacyclopentadiene.

hal.structure.identifierChimie moléculaire et organisation du solide [CMOS]
dc.contributor.authorROQUES, Nans
hal.structure.identifierChimie moléculaire et organisation du solide [CMOS]
hal.structure.identifierInstitut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier [ICGM ICMMM]
dc.contributor.authorGERBIER, Philippe
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorIMAZ, Inhar
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorGUIONNEAU, Philippe
hal.structure.identifierLaboratoire de chimie de coordination [LCC]
dc.contributor.authorSUTTER, Jean-Pascal
dc.date.issued2006
dc.identifier.issn0108-2701
dc.description.abstractEnCrystals of the 1st bis-adduct of 2,5-bis[3-(tert-butylaminoxyl)phenyl]-1,1-dimethyl-3,4-diphenylsilole with bis(hexafluoroacetylacetonato)manganese(II) are monoclinic, space group P21/n; Z = 2. The Mn atom lies on a crystallog. inversion center and is bound to two chelating hexafluoroacetylacetonate ligands and two monodentate nitroxide groups in a distorted octahedral configuration. The silole ligands present a propeller-like arrangement of the benzene rings around the Si-contg. five-membered ring. The dihedral angles between the complexed nitroxides and the benzene rings to which they are bound are smaller than those found in the free ligand.
dc.language.isoen
dc.publisherInternational Union of Crystallography
dc.title.enBis(hexafluoroacetylacetonato)manganese(II) complex of 1,1-dimethyl-2,5-bis-(3-N-tert-butyl-N-phenylaminoxyl) -3,4-diphenylsilolacyclopentadiene.
dc.typeArticle de revue
dc.identifier.doi10.1107/S0108270106020191
dc.subject.halChimie/Chimie organique
dc.subject.halChimie/Cristallographie
dc.subject.halChimie/Chimie de coordination
bordeaux.journalActa Crystallographica Section C : Crystal Structure Communications [1968-2013]
bordeaux.pagem386-m388
bordeaux.volume62
bordeaux.issue9
bordeaux.peerReviewedoui
hal.identifierhal-00186939
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00186939v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Acta%20Crystallographica%20Section%20C%20:%20Crystal%20Structure%20Communications%20%5B1968-2013%5D&rft.date=2006&rft.volume=62&rft.issue=9&rft.spage=m386-m388&rft.epage=m386-m388&rft.eissn=0108-2701&rft.issn=0108-2701&rft.au=ROQUES,%20Nans&GERBIER,%20Philippe&IMAZ,%20Inhar&GUIONNEAU,%20Philippe&SUTTER,%20Jean-Pascal&rft.genre=article


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