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hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorGAUDON, Manuel
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorCARBONERA, Chiara
hal.structure.identifierInstitut des Matériaux Jean Rouxel [IMN]
dc.contributor.authorTHIRY, Anne-Emmanuelle
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorDEMOURGUES, Alain
hal.structure.identifierInstitut des Matériaux Jean Rouxel [IMN]
dc.contributor.authorDENIARD, Philippe
hal.structure.identifierInstitut des Matériaux Jean Rouxel [IMN]
dc.contributor.authorPAYEN, Christophe
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorLÉTARD, Jean-François
hal.structure.identifierInstitut des Matériaux Jean Rouxel [IMN]
dc.contributor.authorJOBIC, Stéphane
dc.date.issued2007
dc.identifier.issn0020-1669
dc.description.abstractEnThe members of the CuMo1 - xWxO4 series (0 x < 0.1) undergo a first-order phase transition at normal pressure, which can be induced by temperature. The two allotropic forms exhibit two distinguishable colors, green for the high-temperature form () and brownish-red for the low temperature one (), which opens up a new market for user-friendly temperature indicators. From X-ray diffraction and microprobe analyses as from optical properties, the tungsten substitution rate for molybdenum is limited to 12%. Beyond, a third, parasitic wolframite-type phase, CuMo0.6W0.4O6, systematically crystallizes besides the /CuMo0.9W0.1O4 compounds. Within the CuMo1 - xWxO4 solid-solution domain, the dependence of the transition temperatures was followed by calorimetry, optical reflectivity, and magnetism...
dc.language.isoen
dc.publisherAmerican Chemical Society
dc.subject.enThermochromism
dc.subject.enPhase Transition
dc.subject.enWolframite
dc.subject.enTungsten
dc.subject.enMolybdenum
dc.subject.enOptical properties
dc.subject.enTemperature
dc.subject.enColors
dc.title.enAdaptable thermochromism in the CuMo1-xWxO4 series (0 < x < 0.1): a behavior related to a first-order phase transition with a transition temperature depending on x
dc.typeArticle de revue
dc.identifier.doi10.1021/ic701263c
dc.subject.halChimie/Matériaux
bordeaux.journalInorganic Chemistry
bordeaux.page10200-10207
bordeaux.volume46
bordeaux.issue24
bordeaux.peerReviewedoui
hal.identifierhal-00189815
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00189815v1
bordeaux.COinSctx_ver=Z39.88-2004&amp;rft_val_fmt=info:ofi/fmt:kev:mtx:journal&amp;rft.jtitle=Inorganic%20Chemistry&amp;rft.date=2007&amp;rft.volume=46&amp;rft.issue=24&amp;rft.spage=10200-10207&amp;rft.epage=10200-10207&amp;rft.eissn=0020-1669&amp;rft.issn=0020-1669&amp;rft.au=GAUDON,%20Manuel&amp;CARBONERA,%20Chiara&amp;THIRY,%20Anne-Emmanuelle&amp;DEMOURGUES,%20Alain&amp;DENIARD,%20Philippe&amp;rft.genre=article


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