Adaptable thermochromism in the CuMo1-xWxO4 series (0 < x < 0.1): a behavior related to a first-order phase transition with a transition temperature depending on x
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | GAUDON, Manuel | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | CARBONERA, Chiara | |
| hal.structure.identifier | Institut des Matériaux Jean Rouxel [IMN] | |
| dc.contributor.author | THIRY, Anne-Emmanuelle | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | DEMOURGUES, Alain | |
| hal.structure.identifier | Institut des Matériaux Jean Rouxel [IMN] | |
| dc.contributor.author | DENIARD, Philippe | |
| hal.structure.identifier | Institut des Matériaux Jean Rouxel [IMN] | |
| dc.contributor.author | PAYEN, Christophe | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | LÉTARD, Jean-François | |
| hal.structure.identifier | Institut des Matériaux Jean Rouxel [IMN] | |
| dc.contributor.author | JOBIC, Stéphane | |
| dc.date.issued | 2007 | |
| dc.identifier.issn | 0020-1669 | |
| dc.description.abstractEn | The members of the CuMo1 - xWxO4 series (0 x < 0.1) undergo a first-order phase transition at normal pressure, which can be induced by temperature. The two allotropic forms exhibit two distinguishable colors, green for the high-temperature form () and brownish-red for the low temperature one (), which opens up a new market for user-friendly temperature indicators. From X-ray diffraction and microprobe analyses as from optical properties, the tungsten substitution rate for molybdenum is limited to 12%. Beyond, a third, parasitic wolframite-type phase, CuMo0.6W0.4O6, systematically crystallizes besides the /CuMo0.9W0.1O4 compounds. Within the CuMo1 - xWxO4 solid-solution domain, the dependence of the transition temperatures was followed by calorimetry, optical reflectivity, and magnetism... | |
| dc.language.iso | en | |
| dc.publisher | American Chemical Society | |
| dc.subject.en | Thermochromism | |
| dc.subject.en | Phase Transition | |
| dc.subject.en | Wolframite | |
| dc.subject.en | Tungsten | |
| dc.subject.en | Molybdenum | |
| dc.subject.en | Optical properties | |
| dc.subject.en | Temperature | |
| dc.subject.en | Colors | |
| dc.title.en | Adaptable thermochromism in the CuMo1-xWxO4 series (0 < x < 0.1): a behavior related to a first-order phase transition with a transition temperature depending on x | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1021/ic701263c | |
| dc.subject.hal | Chimie/Matériaux | |
| bordeaux.journal | Inorganic Chemistry | |
| bordeaux.page | 10200-10207 | |
| bordeaux.volume | 46 | |
| bordeaux.issue | 24 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00189815 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00189815v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Inorganic%20Chemistry&rft.date=2007&rft.volume=46&rft.issue=24&rft.spage=10200-10207&rft.epage=10200-10207&rft.eissn=0020-1669&rft.issn=0020-1669&rft.au=GAUDON,%20Manuel&CARBONERA,%20Chiara&THIRY,%20Anne-Emmanuelle&DEMOURGUES,%20Alain&DENIARD,%20Philippe&rft.genre=article |
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