Thin film lithium ion conducting LiBSO solid electrolyte
hal.structure.identifier | Research Center for Energy Conversion and Storage | |
dc.contributor.author | JOO, K.-H. | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | VINATIER, Philippe | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | PECQUENARD, Brigitte | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | LEVASSEUR, Alain | |
hal.structure.identifier | Research Center for Energy Conversion and Storage | |
dc.contributor.author | SOHN, H.-J. | |
dc.date.issued | 2003 | |
dc.identifier.issn | 0167-2738 | |
dc.description.abstractEn | Thin films of 1–2 μm amorphous solid electrolytes, (1−x)LiBO2–xLi2SO4 (LiBSO), were fabricated by RF magnetron sputtering with a wide range of compositions, i.e. x=0.4–0.8, which are beyond the glass-forming region by conventional melt quenching method. The ionic conductivity of the electrolyte at room temperature increased with x and showed a maximum at x=0.7, about 2.5×10−6 S/cm. For higher x, (x>0.7), the conductivity began to decrease due to the partial crystallization. In addition, the electrolyte was stable up to 5.8 V vs. Li/Li+. LiBSO thin film electrolyte was incorporated into Li/TiS2 microbattery, showing a good cycling performance. | |
dc.language.iso | en | |
dc.publisher | Elsevier | |
dc.subject.en | Lithium borate–lithium sulfate glass | |
dc.subject.en | Thin film electrolyte | |
dc.subject.en | RF sputtering | |
dc.subject.en | Glass-forming region | |
dc.subject.en | Microbattery | |
dc.title.en | Thin film lithium ion conducting LiBSO solid electrolyte | |
dc.type | Article de revue | |
dc.identifier.doi | 10.1016/S0167-2738(03)00163-2 | |
dc.subject.hal | Chimie/Matériaux | |
bordeaux.journal | Solid State Ionics | |
bordeaux.page | 51-59 | |
bordeaux.volume | 160 | |
bordeaux.issue | 1-2 | |
bordeaux.peerReviewed | oui | |
hal.identifier | hal-00195921 | |
hal.version | 1 | |
hal.popular | non | |
hal.audience | Internationale | |
hal.origin.link | https://hal.archives-ouvertes.fr//hal-00195921v1 | |
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