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hal.structure.identifierInstitut de Physique de Rennes [IPR]
dc.contributor.authorCOLLET, Eric
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorGUIONNEAU, Philippe
dc.date.issued2018-03
dc.identifier.issn1631-0748
dc.description.abstractEnIn molecular spin-crossover materials, the spin-state switching is strongly coupled with changes in the structural degrees of freedom, which play a central role in the alteration of functions and mechanisms of transformation from the molecular scale (bond lengths) to the material scale (volume). This article reviews various techniques currently used, ranging from microscopy to diffraction, to study the structural aspects related to spin crossover at different physical scales. Some of the most important recent advances concern the resolution of complex crystal structures, the determination of microstructures, the study of phase coexistence, temporal studies ranging from second to femtosecond, and the description of multistep transition involving intricate ordering of molecules in different electronic states.
dc.description.sponsorshipEtude femtoseconde rayons X et optique de la dynamique ultrarapide de photocommutation de matériaux moléculaires magnétiques
dc.language.isoen
dc.publisherAcadémie des sciences (Paris)
dc.titleÉtudes structurales des matériaux à conversion de spin : de la molécule aux matériaux
dc.title.enStructural analysis of spin-crossover materials: From molecules to materials
dc.typeArticle de revue
dc.identifier.doi10.1016/j.crci.2018.02.003
dc.subject.halPhysique [physics]
dc.subject.halPhysique [physics]/Matière Condensée [cond-mat]
dc.subject.halPhysique [physics]/Matière Condensée [cond-mat]/Science des matériaux [cond-mat.mtrl-sci]
dc.subject.halChimie/Cristallographie
dc.subject.halChimie/Matériaux
bordeaux.journalComptes Rendus. Chimie
bordeaux.page1133-1151
bordeaux.volume21
bordeaux.issue12
bordeaux.peerReviewedoui
hal.identifierhal-01829388
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-01829388v1
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