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hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorGUILMARD, Marianne
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorROUGIER, Aline
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorGRÜNE, M.
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorCROGUENNEC, Laurence
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorDELMAS, Claude
dc.date.issued2003
dc.identifier.issn0378-7753
dc.description.abstractEnLiNi1−yAlyO2 (0.10≤y≤0.50) compounds have been synthesized by a coprecipitation method. The characterization of the samples by X-ray and neutron diffraction, associated with Rietveld refinement analysis, has shown that for all materials, about 5% extra-nickel ions are present in the interslab space. Charge−discharge cycling of LiNi1−yAlyO2 as positive electrode material in lithium cells has shown that aluminum substitution suppresses all the phase transitions observed for the LiNiO2 system. Good cycling stability was observed, but the capacity decreases from 125 to 100 mAh/g by increasing the aluminum amount from 10 to 25% (3–4.15 V range; C/20 rate).
dc.language.isoen
dc.publisherElsevier
dc.subject.enIntercalation
dc.subject.enLithium battery
dc.subject.enLiNiO2
dc.subject.enAluminum substitution
dc.subject.enDiffraction
dc.title.enEffects of aluminum on the structural and electrochemical properties of LiNiO2
dc.typeArticle de revue
dc.identifier.doi10.1016/S0378-7753(03)00012-0
dc.subject.halChimie/Matériaux
bordeaux.journalJournal of Power Sources
bordeaux.page305-314
bordeaux.volume115
bordeaux.issue2
bordeaux.peerReviewedoui
hal.identifierhal-00242745
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00242745v1
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