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Spin crossover properties of the [Fe(PM-BiA)2(NCS)2] complex - phases I and II

hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorLÉTARD, Jean-François
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorCHASTANET, Guillaume
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorNGUYEN, Olivier
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorMARCÉN, Silvia
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorMARCHIVIE, Mathieu
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorGUIONNEAU, Philippe
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorCHASSEAU, Daniel
hal.structure.identifierInsitut für Anorganische und Analytische Chemie
dc.contributor.authorGUTLICH, Philipp
dc.date.issued2003
dc.identifier.issn0026-9247
dc.description.abstractEnIn the present review, we reexamine the photomagnetic properties of the [Fe(PM-BiA)2(NCS)2], cis-bis(thiocyanato)-bis[(N-2'-pyridylmethylene)-4-(aminobiphenyl)]iron(II), compound which exhibits, depending on the synthetic method, an exceptionally abrupt spin transition (phase I) with a very narrow hysteresis (T1/2O = 168 K and T1/2N = 173 K) or a gradual spin conversion (phase II) occurring at 190 K. In both cases, light irradiation in the tail of the 1MLCT-LS absorption band, at 830 nm, results in the population of the high-spin state according to the light-induced excited spin-state trapping (LIESST) effect. The capacity of a compound to retain the light-induced HS information, estimated through the T(LIESST) experiment, is determined for both phases. Interestingly, the shape of the T(LIESST) curve is more gradual for the phase II than for the phase I and the T(LIESST) value is found considerably lower in the case of the phase II. The kinetics parameters involved in the photoinduced high-spinMlow-spin relaxation process are estimated for both phases. From these data, the experimental T(LIESST) curves are simulated and the particular influence of the cooperativity as well as of the parameters involved in the thermally activated and tunneling regions are discussed. The Light-Induced Thermal Hysteresis (LITH), originally described for the strongly cooperative phase I, is also reinvestigated. The quasi-static LITH loop is determined by recording the photostationary points in the warming and cooling branches.
dc.language.isoen
dc.publisherSpringer Verlag
dc.subject.enKinetic relaxation
dc.subject.enSpin crossover
dc.subject.enIron(II)
dc.subject.enPhotomagnetism
dc.subject.enKinetic relaxation.
dc.title.enSpin crossover properties of the [Fe(PM-BiA)2(NCS)2] complex - phases I and II
dc.typeArticle de revue
dc.identifier.doi10.1007/s00706-002-0537-0
dc.subject.halChimie/Matériaux
bordeaux.journalChemical Monthly = Monatshefte für Chemie
bordeaux.page165-182
bordeaux.volume134
bordeaux.issue2
bordeaux.peerReviewedoui
hal.identifierhal-00258375
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00258375v1
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