Characterization of the piezochromic behavior of some members of the CuMo1-xWxO4 series
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | GAUDON, Manuel | |
| hal.structure.identifier | Institut des Matériaux Jean Rouxel [IMN] | |
| dc.contributor.author | THIRY, Anne-Emmanuelle | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | LARGETEAU, Alain | |
| hal.structure.identifier | Institut des Matériaux Jean Rouxel [IMN] | |
| dc.contributor.author | DENIARD, Philippe | |
| hal.structure.identifier | Institut des Matériaux Jean Rouxel [IMN] | |
| dc.contributor.author | JOBIC, Stéphane | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | MAJIMEL, Jérôme | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | DEMOURGUES, Alain | |
| dc.date.issued | 2008 | |
| dc.identifier.issn | 0020-1669 | |
| dc.description.abstractEn | The members of the CuMo1−xWxO4 series (0 ≤ x < 0.1) undergo a first-order phase transition that can be induced by pressure application; the thermochromic properties of such a series have already been reported. The two polymorphic forms exhibit two distinguishable colors: green for the low pressure form (α) and brownish-red for the high pressure one (γ). These oxides can open up a new market for friendly pressure indicators, particularly for the compositions (0.07 ≤ x ≤ 0.1) for which the two polymorphs are stable at room temperature, that is, for which the color transition via pressure application is nonreversible. Within the CuMo1−xWxO4 solid solution domain, the dependence of the transition pressure versus tungsten content, temperature of measurement, and sample thermal-pressure history was studied. A large control of the transition pressure (from 5 to several 100 MPa) was brought to the fore. The transition was then studied using X-ray diffraction and transmission electron microscopy-energy dispersive X-ray analyses. This first-order transition, occurring by atomic migration inside the cell, seems to be preceded by an atomic disordering; moreover, transition temperatures may be modified by W segregation at the surface of the grains. | |
| dc.language.iso | en | |
| dc.publisher | American Chemical Society | |
| dc.subject.en | Inorganic comounds | |
| dc.subject.en | Solid solution | |
| dc.subject.en | Piezochromism | |
| dc.subject.en | X-ray diffraction | |
| dc.subject.en | Transmission eletron microscopy | |
| dc.subject.en | Inorganic comounds | |
| dc.title.en | Characterization of the piezochromic behavior of some members of the CuMo1-xWxO4 series | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1021/ic702282t | |
| dc.subject.hal | Chimie/Matériaux | |
| bordeaux.journal | Inorganic Chemistry | |
| bordeaux.page | 2404-2410 | |
| bordeaux.volume | 47 | |
| bordeaux.issue | 7 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00279714 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00279714v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Inorganic%20Chemistry&rft.date=2008&rft.volume=47&rft.issue=7&rft.spage=2404-2410&rft.epage=2404-2410&rft.eissn=0020-1669&rft.issn=0020-1669&rft.au=GAUDON,%20Manuel&THIRY,%20Anne-Emmanuelle&LARGETEAU,%20Alain&DENIARD,%20Philippe&JOBIC,%20St%C3%A9phane&rft.genre=article |
Files in this item
| Files | Size | Format | View |
|---|---|---|---|
|
There are no files associated with this item. |
|||