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Properties, structure and crystallization study of germano-gallate glasses in the Ga2O3-GeO2-BaO-K2O system

hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
hal.structure.identifierCentre d'Optique, Photonique et Laser [COPL]
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorSKOPAK, Téa
hal.structure.identifierCentre d'Optique, Photonique et Laser [COPL]
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorCALZAVARA, Florian
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
hal.structure.identifierCentre d'Optique, Photonique et Laser [COPL]
dc.contributor.authorLEDEMI, Yannick
hal.structure.identifierLAboratoire de Recherche en Mécanique Appliquée [LARMAUR]
dc.contributor.authorCELARIE, F.
hal.structure.identifierConditions Extrêmes et Matériaux : Haute Température et Irradiation [CEMHTI]
dc.contributor.authorALLIX, Mathieu
hal.structure.identifierConditions Extrêmes et Matériaux : Haute Température et Irradiation [CEMHTI]
dc.contributor.authorVÉRON, Emmanuel
hal.structure.identifierInstitut des Sciences Moléculaires [ISM]
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorDUSSAUZE, Marc
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorCARDINAL, Thierry
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorFARGIN, Evelyne
hal.structure.identifierCentre d'Optique, Photonique et Laser [COPL]
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorMESSADDEQ, Younès
dc.date.issued2019-06
dc.identifier.issn0022-3093
dc.description.abstractEnMid-infrared transparent germano-gallate glasses (with gallium oxide as main component) have been studied following the composition law (100-x)[48.3GaO3/2-32.2GeO2-19.5BaO]-xKO1/2 (with x = 0, 5, 10, 13, 17 mol%). All prepared glasses are transparent from approximately 280 nm up to 5.5 μm, with a measured linear refractive index and density decreasing respectively from 1.72 to 1.67 (at 1538 nm) and 4.79 to 4.34 g/cm3 with increasing potassium oxide content. As expected, the increase of potassium oxide content also results in a decrease of the glass transition temperature (698 to 671 °C) and the viscosity in the softening regime whereas the thermal expansion coefficient increases (4.8 to 10.3 × 10−6 K−1). These results are related to the depolymerization of the 3D interconnected glass network which has been studied by Raman spectroscopy. Large thermal stability criteria (difference between onset of crystallization and glass transition temperatures) ranging from 182 to 199 °C have been measured by DSC for the compositions containing potassium oxide, suggesting strong potential for fiber drawing from glass preforms. The 40.1GaO3/2-26.7GeO2-16.2BaO-17KO1/2 glass composition (in cation mol.%, which corresponds to 28Ga2O3-37GeO2-23BaO-12K2O in mol.%) was then selected for further investigation. Its mechanical properties (Young and shear moduli, Poisson's ratio, hardness) were measured, showing values close to those reported for well-known barium gallo-germanate (BGG) glasses. A thorough crystallization study was then carried out using DSC (Marotta's method), X-Ray diffraction and electron microscopies (TEM and SEM) to better understand the unexpected surface crystallization issues observed during the glass preform fiber drawing process. The potential of using such germano-gallate glasses to produce mid-infrared optical fiber of high mechanical strength is discussed.
dc.description.sponsorshipInitiative d'excellence de l'Université de Bordeaux - ANR-10-IDEX-0003
dc.description.sponsorshipImPRession laser de fibres exOtiques Multi-MaTEriaux - ANR-17-CE08-0042
dc.language.isoen
dc.publisherElsevier
dc.subject.enGermano-gallate glass
dc.subject.enNucleation and growth
dc.subject.enGlass crystallization
dc.subject.enInfrared transparency
dc.subject.enRaman spectroscopy
dc.title.enProperties, structure and crystallization study of germano-gallate glasses in the Ga2O3-GeO2-BaO-K2O system
dc.typeArticle de revue
dc.identifier.doi10.1016/j.jnoncrysol.2019.02.028
dc.subject.halChimie/Matériaux
bordeaux.journalJournal of Non-Crystalline Solids
bordeaux.page98-107
bordeaux.volume514
bordeaux.peerReviewedoui
hal.identifierhal-02098546
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-02098546v1
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