Electron microscopy and structural studies of Nd1/3NbO3
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | ROUDEAU, Sabine | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | PECHEV, Stanislav | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| hal.structure.identifier | Centre de Ressources en Microscopie Electronique et Microanalyse | |
| dc.contributor.author | WEILL, François | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | BASSAT, Jean-Marc. | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | GRENIER, Jean-Claude | |
| dc.date.issued | 2008 | |
| dc.identifier.issn | 1631-0748 | |
| dc.description.abstractEn | The crystal structure of the deficient perovskite Nd1/3NbO3 has been determined at room temperature, using electron microscopy observations and X-ray powder diffraction data. Electron diffraction study and HRTEM images evidence the doubling of a and b parameters and confirm one of the c-parameter with respect to perovskite unit cell. The structure refinement has been carried out using the orthorhombic Cmmm space group. The Nd3+ cations occupy randomly and alternatively the (00l) planes and Nb5+ cations distorted octahedral sites. This structure is characterized by the presence of empty Nd3+ sites in every second layer and the tilting of the octahedral sites around the b-axis. In addition, electron diffraction patterns exhibit weak additional diffuse reflections, which supposes some ordering of the Nd vacancies. | |
| dc.language.iso | en | |
| dc.publisher | Académie des sciences (Paris) | |
| dc.title.en | Electron microscopy and structural studies of Nd1/3NbO3 | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1016/j.crci.2007.10.002 | |
| dc.subject.hal | Chimie/Matériaux | |
| bordeaux.journal | Comptes Rendus. Chimie | |
| bordeaux.page | 734-740 | |
| bordeaux.volume | 11 | |
| bordeaux.issue | 6-7 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00301637 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00301637v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Comptes%20Rendus.%20Chimie&rft.date=2008&rft.volume=11&rft.issue=6-7&rft.spage=734-740&rft.epage=734-740&rft.eissn=1631-0748&rft.issn=1631-0748&rft.au=ROUDEAU,%20Sabine&PECHEV,%20Stanislav&WEILL,%20Fran%C3%A7ois&BASSAT,%20Jean-Marc.&GRENIER,%20Jean-Claude&rft.genre=article |
Fichier(s) constituant ce document
| Fichiers | Taille | Format | Vue |
|---|---|---|---|
|
Il n'y a pas de fichiers associés à ce document. |
|||