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A photoactive copper iodide phosphine-based coordination polymer

hal.structure.identifierPhysique de la Matière Condensée [PMC]
dc.contributor.authorBENITO, Quentin
hal.structure.identifierPhysique de la Matière Condensée [PMC]
dc.contributor.authorDESBOEUFS, Nicolas
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorFARGUES, Alexandre
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorGARCIA, Alain
hal.structure.identifierInstitut des Matériaux Jean Rouxel [IMN]
dc.contributor.authorMASSUYEAU, Florian
hal.structure.identifierInstitut Lavoisier de Versailles [ILV]
hal.structure.identifierConditions Extrêmes et Matériaux : Haute Température et Irradiation [CEMHTI]
dc.contributor.authorMARTINEAU-CORCOS, Charlotte
hal.structure.identifierInstitut des Matériaux Jean Rouxel [IMN]
dc.contributor.authorDEVIC, Thomas
hal.structure.identifierInstitut des Matériaux Jean Rouxel [IMN]
dc.contributor.authorPERRUCHAS, Sandrine
dc.date.issued2020-11-23
dc.identifier.issn1144-0546
dc.description.abstractEnA coordination polymer based on the polymetallic [Cu4I4] center was synthesized by coordination with a phenyl-based-diphosphine ligand. The structure of this solid formulated [Cu4I4(Ph2P(C6H4)2PPh2)2]n, although crystalline, could not be completely resolved by powder X Ray diffraction. Nevertheless, combining different characterization techniques and in particular the 63 Cu and 31 P solid-state NMR analyses, permit to get insights into the polymeric structure. This coordination polymer appears to be of high dimensionally with possible interpenetrated networks, resulting in low porosity. Photoluminescence characterization revealed original luminescence thermochromic properties ascribed to the photoactive [Cu4I4(PPh2-)4] cluster unit.
dc.language.isoen
dc.publisherRoyal Society of Chemistry
dc.subject.enCopper iodide cluster
dc.subject.endiphosphine ligand
dc.subject.encoordination polymer
dc.subject.enluminescence thermochromism
dc.title.enA photoactive copper iodide phosphine-based coordination polymer
dc.typeArticle de revue
dc.identifier.doi10.1039/D0NJ04486E
dc.subject.halPhysique [physics]/Matière Condensée [cond-mat]/Science des matériaux [cond-mat.mtrl-sci]
bordeaux.journalNew Journal of Chemistry
bordeaux.page19850-19857
bordeaux.volume44
bordeaux.issue45
bordeaux.peerReviewedoui
hal.identifierhal-03068397
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-03068397v1
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