A photoactive copper iodide phosphine-based coordination polymer
hal.structure.identifier | Physique de la Matière Condensée [PMC] | |
dc.contributor.author | BENITO, Quentin | |
hal.structure.identifier | Physique de la Matière Condensée [PMC] | |
dc.contributor.author | DESBOEUFS, Nicolas | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | FARGUES, Alexandre | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | GARCIA, Alain | |
hal.structure.identifier | Institut des Matériaux Jean Rouxel [IMN] | |
dc.contributor.author | MASSUYEAU, Florian | |
hal.structure.identifier | Institut Lavoisier de Versailles [ILV] | |
hal.structure.identifier | Conditions Extrêmes et Matériaux : Haute Température et Irradiation [CEMHTI] | |
dc.contributor.author | MARTINEAU-CORCOS, Charlotte | |
hal.structure.identifier | Institut des Matériaux Jean Rouxel [IMN] | |
dc.contributor.author | DEVIC, Thomas | |
hal.structure.identifier | Institut des Matériaux Jean Rouxel [IMN] | |
dc.contributor.author | PERRUCHAS, Sandrine | |
dc.date.issued | 2020-11-23 | |
dc.identifier.issn | 1144-0546 | |
dc.description.abstractEn | A coordination polymer based on the polymetallic [Cu4I4] center was synthesized by coordination with a phenyl-based-diphosphine ligand. The structure of this solid formulated [Cu4I4(Ph2P(C6H4)2PPh2)2]n, although crystalline, could not be completely resolved by powder X Ray diffraction. Nevertheless, combining different characterization techniques and in particular the 63 Cu and 31 P solid-state NMR analyses, permit to get insights into the polymeric structure. This coordination polymer appears to be of high dimensionally with possible interpenetrated networks, resulting in low porosity. Photoluminescence characterization revealed original luminescence thermochromic properties ascribed to the photoactive [Cu4I4(PPh2-)4] cluster unit. | |
dc.language.iso | en | |
dc.publisher | Royal Society of Chemistry | |
dc.subject.en | Copper iodide cluster | |
dc.subject.en | diphosphine ligand | |
dc.subject.en | coordination polymer | |
dc.subject.en | luminescence thermochromism | |
dc.title.en | A photoactive copper iodide phosphine-based coordination polymer | |
dc.type | Article de revue | |
dc.identifier.doi | 10.1039/D0NJ04486E | |
dc.subject.hal | Physique [physics]/Matière Condensée [cond-mat]/Science des matériaux [cond-mat.mtrl-sci] | |
bordeaux.journal | New Journal of Chemistry | |
bordeaux.page | 19850-19857 | |
bordeaux.volume | 44 | |
bordeaux.issue | 45 | |
bordeaux.peerReviewed | oui | |
hal.identifier | hal-03068397 | |
hal.version | 1 | |
hal.popular | non | |
hal.audience | Internationale | |
hal.origin.link | https://hal.archives-ouvertes.fr//hal-03068397v1 | |
bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=New%20Journal%20of%20Chemistry&rft.date=2020-11-23&rft.volume=44&rft.issue=45&rft.spage=19850-19857&rft.epage=19850-19857&rft.eissn=1144-0546&rft.issn=1144-0546&rft.au=BENITO,%20Quentin&DESBOEUFS,%20Nicolas&FARGUES,%20Alexandre&GARCIA,%20Alain&MASSUYEAU,%20Florian&rft.genre=article |
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