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Electrochemical characterization of Li10SnP2S12: An electrolyte or a negative electrode for solid state Li-ion batteries?

hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
hal.structure.identifierRéseau sur le stockage électrochimique de l'énergie [RS2E]
hal.structure.identifierLaboratoire réactivité et chimie des solides - UMR CNRS 7314 [LRCS]
dc.contributor.authorTARHOUCHI, Ilyas
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
hal.structure.identifierRéseau sur le stockage électrochimique de l'énergie [RS2E]
dc.contributor.authorVINATIER, Philippe
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
hal.structure.identifierRéseau sur le stockage électrochimique de l'énergie [RS2E]
dc.contributor.authorMÉNÉTRIER, Michel
hal.structure.identifierRéseau sur le stockage électrochimique de l'énergie [RS2E]
hal.structure.identifierLaboratoire réactivité et chimie des solides - UMR CNRS 7314 [LRCS]
dc.contributor.authorVIALLET, Virginie
dc.date.issued2016
dc.identifier.issn0167-2738
dc.description.abstractEnLi10SnP2S12, the tin analogue of the Li10GeP2S12 superionic conductor is characterized. Rietveld refinement of capillary powder XRD confirms that the material provided by NEI Corp. is mainly composed of Li10SnP2S12 with LGPS structure, with some Li2SnS3 impurity. Very strong reactivity at low voltage and vs. Li metal is shown by impedance measurements using Au and Li electrodes, as well as 3-electrode cyclic voltammetry. Galvanostatic measurements in half-cells with liquid and solid electrolytes confirm that Li10SnP2S12 reacts with respectively 16 and 8 lithium per mole of tin below 0.5 V vs. Li+/Li, most probably following a conversion/alloying reaction. Making use of this reactivity, we tested the concept of a LiCoO2/Li10SnP2S12 cell, were the electrolyte also acts as negative electrode at the contact with the negative current collector. 0.5 Li can be deintercalated from such cells, with very poor reversibility as probably hampered by the conversion/alloying reaction in the solid state, at least with a non-optimized electrode formulation. Although the voltage slowly but strongly relaxes when opening the circuit suggesting propagation of the reaction from the negative electrode to the electrolyte, it does not seem to reach the positive since no short-circuit was observed.
dc.description.sponsorshipLaboratory of excellency for electrochemical energy storage - ANR-10-LABX-0076
dc.language.isoen
dc.publisherElsevier
dc.subject.enLGPS structure
dc.subject.enSulfide
dc.subject.enSolid electrolyte
dc.subject.enElectrochemical properties
dc.subject.enConversion reaction
dc.title.enElectrochemical characterization of Li10SnP2S12: An electrolyte or a negative electrode for solid state Li-ion batteries?
dc.typeArticle de revue
dc.identifier.doi10.1016/j.ssi.2016.08.016
dc.subject.halChimie/Autre
dc.subject.halChimie/Matériaux
bordeaux.journalSolid State Ionics
bordeaux.page18–25
bordeaux.volume296
bordeaux.peerReviewedoui
hal.identifierhal-01370993
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-01370993v1
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