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hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorVIBHU, Vaibhav
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorROUGIER, Aline
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorNICOLLET, Clément
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorFLURA, Aurélien
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorGRENIER, Jean-Claude
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorBASSAT, Jean-Marc.
dc.date.issued2015
dc.identifier.issn0167-2738
dc.description.abstractEnAiming at a tradeoff between the chemical stability of La2NiO4 + δ (LNO) and the high electrochemical performances of Pr2NiO4 + δ (PNO), La2 − xPrxNiO4 + δ mixed nickelates, further referred as LPNO, were studied as possible oxygen electrodes for solid oxide fuel cells (SOFCs). LPNO phases were synthesized using the modified citrate–nitrate route followed by a heat treatment at 1200 °C for 12 h under air. Structural characterizations of those K2NiF4-type compounds show the existence of two solid solutions with orthorhombic structure, namely a La-rich one from x = 0 to 0.5 with Fmmm space group, and a Pr-rich one from x = 1.0 to 2.0 with Bmab space group. The mixed ionic and electronic conducting (MIEC) properties of LPNO phases were investigated through the evolution of the oxygen over-stoichiometry, δ, measured as a function of temperature and pO2, the electrical conductivity, the diffusion and surface exchange coefficients versus x, showing that all compositions exhibit suitable characteristics as cathode materials for SOFCs. In particular, the electrochemical performances measured in symmetrical cells using LPNO materials sintered under low pO2, as requested in metal supported cell, (MSC-conditions) confirmed a decrease in polarization resistance values, Rp, from 0.93 Ω cm2 (LNO) down to 0.15 Ω cm2 (PNO) at 600 °C with increasing x.
dc.description.sponsorshipPerformance Et Robustesse pour les cellules d'Electrolyse haute température de Nouvelle génération - ANR-11-PRGE-0016
dc.language.isoen
dc.publisherElsevier
dc.subject.enSOFCs
dc.subject.enMetal supported cells
dc.subject.enOxygen over-stoichiometry
dc.subject.enLanthanum–praseodymium mixed nickelates
dc.subject.enOxygen diffusivity
dc.subject.enMetal Supported Cells
dc.subject.enoxygen over-stoichiometry
dc.subject.enlanthanumpraseodymium mixed nickelates
dc.subject.enoxygen diffusivity
dc.title.enLa2-xPrxNiO4+δ as suitable cathodes for metal supported SOFCs
dc.typeArticle de revue
dc.identifier.doi10.1016/j.ssi.2015.05.005
dc.subject.halChimie/Matériaux
bordeaux.journalSolid State Ionics
bordeaux.page32-37
bordeaux.volume278
bordeaux.peerReviewedoui
hal.identifierhal-01171838
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-01171838v1
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