Discrete FeII spin-crossover complexes of 2,2'-dipyridylamino- substituted s-triazine ligands with phenoxo, cyanophenoxo and dibenzylamino functionalities
| hal.structure.identifier | School of Chemistry | |
| dc.contributor.author | SCOTT, Haley S. | |
| hal.structure.identifier | School of Chemistry | |
| dc.contributor.author | ROSS, Tamsyn M. | |
| hal.structure.identifier | School of Chemistry | |
| dc.contributor.author | PHONSRI, Wasinee | |
| hal.structure.identifier | School of Chemistry | |
| dc.contributor.author | MOUBARAKI, Boujemaa | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | CHASTANET, Guillaume | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | LÉTARD, Jean-Francois | |
| hal.structure.identifier | School of Chemistry | |
| hal.structure.identifier | Department of Chemistry | |
| dc.contributor.author | BATTEN, Stuart R. | |
| hal.structure.identifier | School of Chemistry | |
| dc.contributor.author | MURRAY, Keith S. | |
| dc.date.issued | 2015 | |
| dc.identifier.issn | 1434-1948 | |
| dc.description.abstractEn | Four 2,2′-dipyridylamino-s-triazine-substituted ligands, each of which incorporate different aromatic substituents (phenoxo, 4-CN-phenoxo and benzylamino) with different degrees of bulk and flexibility, have been formed and incorporated into a number of mononuclear FeII complexes of type trans-[FeII(L)2(NCX)2]·solvent (in which X = S, Se and BH3). These ligands were designed to promote π–π stacking between complexes. The complexes reported have been comprehensively characterised using single-crystal diffraction techniques in combination with magnetic susceptibility measurements. Light-induced excited spin-state trapping (LIESST) measurements have been performed on selected complexes. Light irradiation has shown the occurrence of a reversible photoswitching process at low temperature. | |
| dc.language.iso | en | |
| dc.publisher | Wiley-VCH Verlag | |
| dc.subject.en | Spin crossover | |
| dc.subject.en | Structure elucidation | |
| dc.subject.en | Cooperative phenomena | |
| dc.subject.en | Iron | |
| dc.subject.en | Magnetic properties | |
| dc.title.en | Discrete FeII spin-crossover complexes of 2,2'-dipyridylamino- substituted s-triazine ligands with phenoxo, cyanophenoxo and dibenzylamino functionalities | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1002/ejic.201402972 | |
| dc.subject.hal | Chimie/Matériaux | |
| bordeaux.journal | European Journal of Inorganic Chemistry | |
| bordeaux.page | 763-777 | |
| bordeaux.issue | 5 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-01116558 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-01116558v1 | |
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