A new mixed ligand coordination polymer of Mn(II): structural aspect and cryomagnetic study
| hal.structure.identifier | Department of Chemistry | |
| dc.contributor.author | SHIT, Shyamapada | |
| hal.structure.identifier | Department of Chemistry | |
| dc.contributor.author | CHAKRABORTY, Joy | |
| hal.structure.identifier | Chemical Crystallography Group, Chemistry Department | |
| dc.contributor.author | HOWARD, Judith A. K. | |
| hal.structure.identifier | Chemical Crystallography Group, Chemistry Department | |
| dc.contributor.author | SPENCER, E. C. | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | DESPLANCHES, Cédric | |
| hal.structure.identifier | Department of Chemistry | |
| dc.contributor.author | MITRA, Samiran | |
| dc.date.issued | 2008 | |
| dc.identifier.issn | 1040-0400 | |
| dc.description.abstractEn | A new 1-D polymeric chain complex [Mn(pydc)(1,10-phen)]n· nH2O (pydc = pyridine-2,3-dicarboxylate, 1,10-phen = 1,10-phenanthroline) has been synthesised and characterised by elemental analysis, FT-IR spectrum, thermal analysis and variable temperature magnetic susceptibility studies. Single crystal X-ray diffraction study reveals that the central Mn(II) ion is in a distorted octahedral coordination geometry, and is coordinated to pydc and 1,10-phen. The complex shows interesting hydrogen bond modes involving the dicarboxylates and lattice water molecules. The presence of weak antiferromagnetic coupling with J = −0.72 cm−1 for the complex has been concluded from the cryomagnetic susceptibility studies. | |
| dc.language.iso | en | |
| dc.publisher | Springer Verlag (Germany) | |
| dc.subject.en | Mn(II) | |
| dc.subject.en | 1-D polymer | |
| dc.subject.en | X-ray structure | |
| dc.subject.en | Thermal analysis | |
| dc.subject.en | Antiferromagnetic | |
| dc.title.en | A new mixed ligand coordination polymer of Mn(II): structural aspect and cryomagnetic study | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1007/s11224-008-9324-9 | |
| dc.subject.hal | Chimie/Matériaux | |
| dc.subject.hal | Chimie/Chimie organique | |
| dc.subject.hal | Chimie/Chimie inorganique | |
| bordeaux.journal | Structural Chemistry | |
| bordeaux.page | 553-558 | |
| bordeaux.volume | 19 | |
| bordeaux.issue | 4 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00319597 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00319597v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Structural%20Chemistry&rft.date=2008&rft.volume=19&rft.issue=4&rft.spage=553-558&rft.epage=553-558&rft.eissn=1040-0400&rft.issn=1040-0400&rft.au=SHIT,%20Shyamapada&CHAKRABORTY,%20Joy&HOWARD,%20Judith%20A.%20K.&SPENCER,%20E.%20C.&DESPLANCHES,%20C%C3%A9dric&rft.genre=article |
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