Surface modification of carbonaceous materials by fluorinated gases and use as anode in lithium-ion battery
hal.structure.identifier | Liquides Ioniques et Interfaces Chargées [LI2C] | |
dc.contributor.author | GROULT, Henri | |
hal.structure.identifier | Aichi Institute of Technology [AIT] | |
dc.contributor.author | NAKAJIMA, Tsuyoshi | |
hal.structure.identifier | Liquides Ioniques et Interfaces Chargées [LI2C] | |
dc.contributor.author | PERRIGAUD, Laurent | |
hal.structure.identifier | Centre de Recherche sur la Matière Divisée [CRMD] | |
dc.contributor.author | WARMONT, Fabienne | |
hal.structure.identifier | Aichi Institute of Technology [AIT] | |
dc.contributor.author | OHZAWA, Yoshimi | |
hal.structure.identifier | Laboratoire de Dynamique Interactions et Réactivité [LADIR] | |
dc.contributor.author | BADDOUR-HADJEAN, Rita | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | TRESSAUD, A. | |
hal.structure.identifier | Institut des Nanosciences de Paris [INSP] | |
dc.contributor.author | JULIEN, Christian | |
dc.date.issued | 2007 | |
dc.identifier.issn | 1938-5862 | |
dc.description.abstractEn | The electrochemical performances of raw and surface- fluorinated graphite powders used as anode in Li-ion battery have been studied. The fluorination obtained from F2 gas mainly concerns the surface of the particles for TF2≤300 {degree sign}C. For higher temperature, important modifications of the bulk structure were observed. When they are used as anode in Li-ion battery, fluorinated graphite powders exhibit better electrochemical performances than raw graphite notably due to an increase of the surface area and surface defects which allow the storage of a higher amount of lithium into the host lattice. These results have been confirmed by impedance measurements performed in delithiated state: a drastic decrease of both the charge transfer resistance and the resistance related to the SEI layer was observed for TF2 lower than 300 {degree sign}C. | |
dc.language.iso | en | |
dc.publisher | Electrochemical Society, Inc. | |
dc.title.en | Surface modification of carbonaceous materials by fluorinated gases and use as anode in lithium-ion battery | |
dc.type | Article de revue | |
dc.identifier.doi | 10.1149/1.2795118 | |
dc.subject.hal | Physique [physics]/Physique [physics]/Chimie-Physique [physics.chem-ph] | |
bordeaux.journal | ECS Transactions | |
bordeaux.page | 167-176 | |
bordeaux.volume | 3 | |
bordeaux.issue | 36 | |
bordeaux.peerReviewed | oui | |
hal.identifier | hal-00165334 | |
hal.version | 1 | |
hal.popular | non | |
hal.audience | Internationale | |
hal.origin.link | https://hal.archives-ouvertes.fr//hal-00165334v1 | |
bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=ECS%20Transactions&rft.date=2007&rft.volume=3&rft.issue=36&rft.spage=167-176&rft.epage=167-176&rft.eissn=1938-5862&rft.issn=1938-5862&rft.au=GROULT,%20Henri&NAKAJIMA,%20Tsuyoshi&PERRIGAUD,%20Laurent&WARMONT,%20Fabienne&OHZAWA,%20Yoshimi&rft.genre=article |
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