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hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorDARRIET, Jacques
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorGRASSET, Fabien
hal.structure.identifierInorganic Chemistry Laboratory [Oxford]
dc.contributor.authorBATTLE, Peter
dc.date.issued1997-02
dc.identifier.issn0025-5408
dc.description.abstractEnThe compounds A3A′RuO6 (A = Ca, Sr; A′ = Li, Na) have been synthesized by solid state reactions and studied by X-ray powder diffraction and magnetometry. They all adopt the K4CdCl6 (Sr4PtO6) structure with the cations A′ and Ru occupying the trigonal prismatic and octahedral sites respectively. Infinite chains of octahedra and trigonal prisms sharing faces run parallel to the c axis, the chains being separated by the cations A (Ca, Sr). The validity of this description of the structure is discussed in the light of magnetic susceptibility data which suggest that these phases all transform to a magnetically ordered state in the temperature range 70 < T/K < 120. Preliminary results of powder neutron diffraction experiments confirm the presence of long-range magnetic order in the low temperature phase.
dc.language.isoen
dc.publisherElsevier
dc.title.enSynthesis, crystal structure and magnetic properties of A3A′RuO6 (A = Ca, Sr; A′ = Li, Na)
dc.typeArticle de revue
dc.identifier.doi10.1016/S0025-5408(96)00183-3
dc.subject.halChimie/Matériaux
dc.subject.halChimie
dc.subject.halChimie/Chimie inorganique
bordeaux.journalMaterials Research Bulletin
bordeaux.page139-150
bordeaux.volume32
bordeaux.issue2
bordeaux.peerReviewedoui
hal.identifierhal-03070409
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-03070409v1
bordeaux.COinSctx_ver=Z39.88-2004&amp;rft_val_fmt=info:ofi/fmt:kev:mtx:journal&amp;rft.jtitle=Materials%20Research%20Bulletin&amp;rft.date=1997-02&amp;rft.volume=32&amp;rft.issue=2&amp;rft.spage=139-150&amp;rft.epage=139-150&amp;rft.eissn=0025-5408&amp;rft.issn=0025-5408&amp;rft.au=DARRIET,%20Jacques&amp;GRASSET,%20Fabien&amp;BATTLE,%20Peter&amp;rft.genre=article


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