Electrochemical, vibrational, optical and Hirshfeld surface studies of 3D- bis[di(1,10-phenanthrolinium) (1,10-phenanthroline)] hexacyanoferrate ethanol trihydrate
| hal.structure.identifier | Laboratory of Nanomaterials and Renewable Energy | |
| hal.structure.identifier | Laboratory of Materials Crystal Chemistry and Applied Thermodynamics [LR15SR01] | |
| dc.contributor.author | SELMI, Wafa | |
| hal.structure.identifier | Laboratory of Analytical Chemistry and Electrochemistry | |
| dc.contributor.author | HOSNI, Nabil | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | MARCHIVIE, Mathieu | |
| hal.structure.identifier | Laboratory of Nanomaterials and Renewable Energy | |
| dc.contributor.author | NACEUR, J. Ben | |
| hal.structure.identifier | Laboratory of Analytical Chemistry and Electrochemistry | |
| dc.contributor.author | MAGHRAOUI-MEHERZI, Hager | |
| hal.structure.identifier | Laboratory of Materials Crystal Chemistry and Applied Thermodynamics [LR15SR01] | |
| dc.contributor.author | ZID, Mohamed F. | |
| dc.date.issued | 2022-04 | |
| dc.identifier.issn | 0022-2860 | |
| dc.description.abstractEn | In this work, structure, spectroscopic, optical and electrochemical investigation of a new complex of the hexacyanoferrate [Fe(CN)(6)](4-) and 1,10-phenanthroline have been examined. The complex has been resolved by single crystal X-ray diffraction at room temperature. In the crystal structure individual complex is interconnected through strong hydrogen bonds of type O-H...N, N-H...O and pi-pi interactions to obtain a 3D supramolecular shape. The three-dimensional Hirshfeld surface (3D-HS) investigation and the two-dimensional unique finger impression plots (2D-FP) reveal that the H... O, H... N and H... H contacts dominates the structure. The cyclic voltammetry explores the electrochemical performance of the complex. The complex reveals excellent supercapacitives properties with a higher specific capacitance equal to 1000 F.g(-1) for the scans rate 10 mVs(-1). | |
| dc.language.iso | en | |
| dc.publisher | Elsevier | |
| dc.title.en | Electrochemical, vibrational, optical and Hirshfeld surface studies of 3D- bis[di(1,10-phenanthrolinium) (1,10-phenanthroline)] hexacyanoferrate ethanol trihydrate | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1016/j.molstruc.2021.132320 | |
| dc.subject.hal | Chimie/Matériaux | |
| bordeaux.journal | Journal of Molecular Structure | |
| bordeaux.page | 132320 (8 p.) | |
| bordeaux.volume | 1254 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-03631697 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-03631697v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Journal%20of%20Molecular%20Structure&rft.date=2022-04&rft.volume=1254&rft.spage=132320%20(8%20p.)&rft.epage=132320%20(8%20p.)&rft.eissn=0022-2860&rft.issn=0022-2860&rft.au=SELMI,%20Wafa&HOSNI,%20Nabil&MARCHIVIE,%20Mathieu&NACEUR,%20J.%20Ben&MAGHRAOUI-MEHERZI,%20Hager&rft.genre=article |
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