Laser induced spin state transition: Spectral and temporal evolution
hal.structure.identifier | Centre de physique moléculaire optique et hertzienne [CPMOH] | |
dc.contributor.author | FOUCHÉ, Olivier | |
hal.structure.identifier | Centre de physique moléculaire optique et hertzienne [CPMOH] | |
dc.contributor.author | DEGERT, Jérôme | |
hal.structure.identifier | Centre de physique moléculaire optique et hertzienne [CPMOH] | |
dc.contributor.author | JONUSAUSKAS, Gediminas | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | BALDE, Cherif | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | DESPLANCHES, Cédric | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | LÉTARD, Jean-François | |
hal.structure.identifier | Centre de physique moléculaire optique et hertzienne [CPMOH] | |
dc.contributor.author | FREYSZ, Eric | |
dc.date.issued | 2009 | |
dc.identifier.issn | 0009-2614 | |
dc.description.abstractEn | At 150 K, we have recorded the evolution of the energy threshold versus the wavelength and the kinetic of formation and relaxation of the spin state phase transition induced by a single laser pulse in the [Fe(PM-BiA)<sub>2</sub>(NCS)<sub>2</sub>] compound. We demonstrate that different absorption bands of the complexes can drive the phase transition. The saturation-energy and the threshold-energy of the laser pulses are not directly related to the absorption cross-section of the sample. Both the switching and the relaxation kinetics are well fitted using two different time-constants. The switching lasts about 50 μs. The relaxation time-constants are independent of the used excitation-wavelength. | |
dc.language.iso | en | |
dc.publisher | Elsevier | |
dc.title.en | Laser induced spin state transition: Spectral and temporal evolution | |
dc.type | Article de revue | |
dc.identifier.doi | 10.1016/j.cplett.2008.12.070 | |
dc.subject.hal | Chimie/Matériaux | |
bordeaux.journal | Chemical Physics Letters | |
bordeaux.page | 274-278 | |
bordeaux.volume | 469 | |
bordeaux.issue | 4-6 | |
bordeaux.peerReviewed | oui | |
hal.identifier | hal-00365464 | |
hal.version | 1 | |
hal.popular | non | |
hal.audience | Internationale | |
hal.origin.link | https://hal.archives-ouvertes.fr//hal-00365464v1 | |
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