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Spin crossover or intra-molecular electron transfer in a cyanido-bridged Fe/Co dinuclear dumbbell : a matter of state

hal.structure.identifierCentre de recherches Paul Pascal [CRPP]
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorJEON, Ie-Rang
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorCALANCEA, Sergui
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorPANJA, Anangamohan
hal.structure.identifierCentre de recherches Paul Pascal [CRPP]
dc.contributor.authorPIÑERO CRUZ, Dalice M.
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorKOUMOUSI, Evangelia S.
hal.structure.identifierCentre de recherches Paul Pascal [CRPP]
dc.contributor.authorDECHAMBENOIT, Pierre
hal.structure.identifierCentre de recherches Paul Pascal [CRPP]
dc.contributor.authorCOULON, Claude
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorWATTIAUX, Alain
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorROSA, Patrick
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorMATHONIÈRE, Corine
hal.structure.identifierCentre de recherches Paul Pascal [CRPP]
dc.contributor.authorCLÉRAC, Rodolphe
dc.date.issued2013
dc.identifier.issn2041-6520
dc.description.abstractEnThe design of molecule-based systems displaying tuneable optical and/or magnetic properties under external stimuli has received a great deal of attention in the past few years. This interest is driven by the potential applications in high-performance molecule-based electronics in the areas of recording media, switches, sensors, and displays. As an example, three-dimensional Fe/Co Prussian blue compounds exhibit a concomitant change in magnetic and optical properties due to a temperature- or light-induced metal-to-metal electron transfer. The foregoing remarkable properties in Prussian blues prompted us to design soluble molecular fragments of these coordination networks through a rational building-block approach in order to mimic their properties on a single molecule. With a judicious choice of the ligands for the iron and cobalt molecular precursors, we prepared a dinuclear cyanido-bridged Fe/Co complex that exhibits an unexpected temperature-dependent spin crossover in the solid state while an intramolecular electron transfer triggered by protonation is observed in solution.
dc.language.isoen
dc.publisherThe Royal Society of Chemistry
dc.title.enSpin crossover or intra-molecular electron transfer in a cyanido-bridged Fe/Co dinuclear dumbbell : a matter of state
dc.typeArticle de revue
dc.identifier.doi10.1039/C3SC22069A
dc.subject.halChimie/Chimie de coordination
bordeaux.journalChemical Science
bordeaux.page2463-2470
bordeaux.volume4
bordeaux.issue6
bordeaux.peerReviewedoui
hal.identifierhal-00822158
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00822158v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Chemical%20Science&rft.date=2013&rft.volume=4&rft.issue=6&rft.spage=2463-2470&rft.epage=2463-2470&rft.eissn=2041-6520&rft.issn=2041-6520&rft.au=JEON,%20Ie-Rang&CALANCEA,%20Sergui&PANJA,%20Anangamohan&PI%C3%91ERO%20CRUZ,%20Dalice%20M.&KOUMOUSI,%20Evangelia%20S.&rft.genre=article


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