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Calcium carbonate: controlled synthesis, surface functionalization, and nanostructured materials

hal.structure.identifierState Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology
hal.structure.identifierQing Yang Institute for Industrial Minerals
dc.contributor.authorNIU, Yu-Qin
hal.structure.identifierState Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology
hal.structure.identifierQing Yang Institute for Industrial Minerals
dc.contributor.authorLIU, Jia-Hui
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorAYMONIER, Cyril
hal.structure.identifierDepartment of Chemistry “Giacomo Ciamician”
dc.contributor.authorFERMANI, Simona
hal.structure.identifierRudjer Boskovic Institute [Zagreb]
dc.contributor.authorKRALJ, Damir
hal.structure.identifierDepartment of Chemistry “Giacomo Ciamician”
dc.contributor.authorFALINI, Giuseppe
hal.structure.identifierState Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology
hal.structure.identifierQing Yang Institute for Industrial Minerals
dc.contributor.authorZHOU, Chun-Hui
dc.date.issued2022
dc.identifier.issn0306-0012
dc.description.abstractEnCalcium carbonate (CaCO3) is an important inorganic mineral in biological and geological systems. Traditionally, it is widely used in plastics, papermaking, ink, building materials, textiles, cosmetics, and food. Over the last decade, there has been rapid development in the controlled synthesis and surface modification of CaCO3, the stabilization of amorphous CaCO3 (ACC), and CaCO3-based nanostructured materials. In this review, the controlled synthesis of CaCO3 is first examined, including Ca2+–CO32− systems, solid–liquid–gas carbonation, water-in-oil reverse emulsions, and biomineralization. Advancing insights into the nucleation and crystallization of CaCO3 have led to the development of efficient routes towards the controlled synthesis of CaCO3 with specific sizes, morphologies, and polymorphs. Recently-developed surface modification methods of CaCO3 include organic and inorganic modifications, as well as intensified surface reactions. The resultant CaCO3 can then be further engineered via template-induced biomineralization and layer-by-layer assembly into porous, hollow, or core–shell organic–inorganic nanocomposites. The introduction of CaCO3 into nanostructured materials has led to a significant improvement in the mechanical, optical, magnetic, and catalytic properties of such materials, with the resultant CaCO3-based nanostructured materials showing great potential for use in biomaterials and biomedicine, environmental remediation, and energy production and storage. The influences that the preparation conditions and additives have on ACC preparation and stabilization are also discussed. Studies indicate that ACC can be used to construct environmentally-friendly hybrid films, supramolecular hydrogels, and drug vehicles. Finally, the existing challenges and future directions of the controlled synthesis and functionalization of CaCO3 and its expanding applications are highlighted.
dc.language.isoen
dc.publisherRoyal Society of Chemistry
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/
dc.title.enCalcium carbonate: controlled synthesis, surface functionalization, and nanostructured materials
dc.typeArticle de revue
dc.identifier.doi10.1039/D1CS00519G
dc.subject.halChimie/Chimie inorganique
dc.subject.halChimie/Matériaux
bordeaux.journalChemical Society Reviews
bordeaux.page7883-7943
bordeaux.volume51
bordeaux.issue18
bordeaux.peerReviewedoui
hal.identifierhal-03760034
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-03760034v1
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