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Hydrogen phenylphosphonate phenylphosphonic acid water 1:1:1 co-crystal and hydrogen phenylarsonate cyclohexylammonium salts : synthesis and crystal elucidation

hal.structure.identifierLaboratoire de Chimie Minerale et Analytique
dc.contributor.authorBIRAME DIOP, Mouhamadou
hal.structure.identifierLaboratoire de Chimie Minerale et Analytique
dc.contributor.authorSARR, Modou
hal.structure.identifierLaboratoire de Chimie Minerale et Analytique
hal.structure.identifierDépartement de Physique-Chimie
dc.contributor.authorSEMBENE BOYE, Mouhamadou
hal.structure.identifierLaboratoire de Chimie Minerale et Analytique
dc.contributor.authorDIASSE-SARR, Aminata
hal.structure.identifierLaboratoire de Chimie Minerale et Analytique
dc.contributor.authorDIOP, Libasse
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorPECHEV, Stanislav
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorGUIONNEAU, Philippe
dc.date.issued2022
dc.identifier.issn2320-5407
dc.description.abstractEnOne pot reactions of phenylphosphonic acid or phenylarsonic acid with cyclohexylamine led to two new organic-inorganic hybrid salts [C6H14N][C6H5PO3H.C6H5PO3H2.H2O] (1) and [(C6H14N)(C6H5AsO3H)] (2) which were investigated by single-crystal X-ray diffraction analysis. Salt 1 crystallizes in the monoclinic system, space group P21/n with h a = 12.3963 (4), b = 6.1123 (2), c =28.2081 (8) Å, β = 90.426 (1)°, V = 2137.27 (12) Å3 and Z = 4. Salt 2 crystallizes in the monoclinic system, space group P21/c with a =12.3991 (5), b = 6.5048 (2), c = 18.5466 (7) Å, β = 105.824 (2)°, V =1439.16 (9) Å3 and Z = 4. In the co-crystal 1, the hydrogen phenylphosphonate anions are organized into dimers via O–H···O H bonds, whereas the phenylphosphonic acid and the water molecules are connected, through Owater–H···O and O–H···O hydrogen bonding interactions, to form dimers. Inter-species O–H···O hydrogen bonds connect the alternating dimers into anionic infinite chains. The 1D infinite ribbons are linked into an anionic 2D layer-like structure, by means of water molecules through O water–H···O and O–H···O water. The cyclohexylammonium interacts via N–H···O hydrogen bonds, to consolidate the compactness of the 2D layer-like structure. In the crystal of salt 2, the hydrogen phenylarsonate anions are organized into dimers through O–H···O H-bonds. Hydrogen bonded dimers are connected by the cyclohexylammonium cations, through N–H···O hydrogen bonds, leading to the formation of an infinite ribbon. The 1D hydrogen bonded ribbons are interlinked through N–H···Ohydrogen bonding interactions giving rise to a 2D layer-like structure.
dc.language.isoen
dc.publisherInternational journal of advanced research
dc.subject.enSingle Crystal X-ray
dc.subject.enPhenylphosphonate
dc.subject.enPhenylarsonate
dc.subject.enCyclohexylammonium
dc.subject.en2D Layer-Like Structure
dc.title.enHydrogen phenylphosphonate phenylphosphonic acid water 1:1:1 co-crystal and hydrogen phenylarsonate cyclohexylammonium salts : synthesis and crystal elucidation
dc.typeArticle de revue
dc.identifier.doi10.21474/IJAR01/14756
dc.subject.halChimie/Matériaux
dc.subject.halChimie/Cristallographie
bordeaux.journalInternational journal of advanced research
bordeaux.page690-700
bordeaux.volume10
bordeaux.issue05
bordeaux.peerReviewedoui
hal.identifierhal-03770005
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-03770005v1
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