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Anion, solvent and time dependence of high-spin-low-spin interactions in a 3D coordination polymer

hal.structure.identifierDepartment of Chemistry
dc.contributor.authorJAMESON, Guy N. L.
hal.structure.identifierCollege of Science and Engineering
dc.contributor.authorWERNER, Frank
hal.structure.identifierInstitute of Applied Synthetic Chemistry
dc.contributor.authorBARTEL, Matthias
hal.structure.identifierInstitute of Applied Synthetic Chemistry
dc.contributor.authorABSMEIER, Alina
hal.structure.identifierInstitute for Solid State Physics
dc.contributor.authorREISSNER, Michael
hal.structure.identifierDepartment of Chemistry
dc.contributor.authorKITCHEN, Jonathan A.
hal.structure.identifierDepartment of Chemistry
dc.contributor.authorBROOKER, Sally
hal.structure.identifierDipartimento di Chimica & UdR INSTM [LAMM]
dc.contributor.authorCANESCHI, Andrea
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorCARBONERA, Chiara
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorLETARD, Jean-François
hal.structure.identifierInstitute of Applied Synthetic Chemistry
dc.contributor.authorLINERT, Wolfgang
dc.date.issued2009
dc.identifier.issn1434-1948
dc.description.abstractEnA thorough investigation into the role of the counterion and occluded solvent on the structure and spin-crossover behaviour of the threefold interpenetrated network [Fe(4ditz)3]2+ [4ditz = 1,4-bis(tetrazol-1-yl)butane] is presented. As seen by X-ray single crystal diffraction, changing the hexafluorophosphate anion in the previously investigated trigonal phase [Fe(4ditz)3](PF6)2 to tetrafluoroborate causes the butylene spacers to adopt three different conformations, whereupon the symmetry is reduced to triclinic (space group P1¯). X-ray powder diffraction and NMR spectroscopy provide evidence for the incorporation of statistically distributed ethanol molecules in the cavities of the compound, whose amount...
dc.language.isoen
dc.publisherWiley-VCH Verlag
dc.title.enAnion, solvent and time dependence of high-spin-low-spin interactions in a 3D coordination polymer
dc.typeArticle de revue
dc.identifier.doi10.1002/ejic.200900537
dc.subject.halChimie/Matériaux
bordeaux.journalEuropean Journal of Inorganic Chemistry
bordeaux.page3948-3959
bordeaux.issue26
bordeaux.peerReviewedoui
hal.identifierhal-00435053
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00435053v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=European%20Journal%20of%20Inorganic%20Chemistry&rft.date=2009&rft.issue=26&rft.spage=3948-3959&rft.epage=3948-3959&rft.eissn=1434-1948&rft.issn=1434-1948&rft.au=JAMESON,%20Guy%20N.%20L.&WERNER,%20Frank&BARTEL,%20Matthias&ABSMEIER,%20Alina&REISSNER,%20Michael&rft.genre=article


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