JAMESON, Guy N. L.; WERNER, Frank; BARTEL, Matthias; ABSMEIER, Alina; REISSNER, Michael; KITCHEN, Jonathan A.; BROOKER, Sally; CANESCHI, Andrea; CARBONERA, Chiara; LETARD, Jean-François; LINERT, Wolfgang

doi:10.1002/ejic.200900537

Métadonnées

Afficher la notice complète

Licence d’utilisation du document

JAMESON, Guy N. L.
Department of Chemistry

WERNER, Frank
College of Science and Engineering

BARTEL, Matthias
Institute of Applied Synthetic Chemistry

Langue

Article de revue

Ce document a été publié dans

European Journal of Inorganic Chemistry. 2009 n° 26, p. 3948-3959

Wiley-VCH Verlag

Résumé en anglais

A thorough investigation into the role of the counterion and occluded solvent on the structure and spin-crossover behaviour of the threefold interpenetrated network [Fe(4ditz)3]2+ [4ditz = 1,4-bis(tetrazol-1-yl)butane] is presented. As seen by X-ray single crystal diffraction, changing the hexafluorophosphate anion in the previously investigated trigonal phase [Fe(4ditz)3](PF6)2 to tetrafluoroborate causes the butylene spacers to adopt three different conformations, whereupon the symmetry is reduced to triclinic (space group P1¯). X-ray powder diffraction and NMR spectroscopy provide evidence for the incorporation of statistically distributed ethanol molecules in the cavities of the compound, whose amount...< Réduire

Métadonnées

Licence d’utilisation du document

Anion, solvent and time dependence of high-spin-low-spin interactions in a 3D coordination polymer

Langue

Ce document a été publié dans

Résumé en anglais

DOI

Origine

Unités de recherche