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Substantial exchange coupling for {Mo-NCS-M} combination: illustration for 1-D [{Mo(NCS)6}{NiL}2(NCS)]n.

hal.structure.identifierLaboratoire de chimie de coordination [LCC]
dc.contributor.authorMOUSAVI, Maliheh
hal.structure.identifierLaboratoire de chimie de coordination [LCC]
dc.contributor.authorBÉREAU, Virginie
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorDESPLANCHES, Cédric
hal.structure.identifierLaboratoire de chimie de coordination [LCC]
dc.contributor.authorGUYARD-DUHAYON, Carine
hal.structure.identifierLaboratoire de chimie de coordination [LCC]
dc.contributor.authorSUTTER, Jean-Pascal
dc.date.issued2010-10-28
dc.identifier.issn1359-7345
dc.description.abstractEnAn antiferromagnetic interaction of J = -51 cm(-1) has been obtained in a NCS-bridged {Mo(III)-Ni} compound (i.e. [{Mo(NCS)(6)}{NiL}(2)(NCS)](n)), a value twice as large as for the homologous {Cr(III)-Ni} derivative. The DFT calculated spin distribution on {Mo(NCS)(6)}(3-) reveals noticeable spin on the S atoms.
dc.language.isoen
dc.publisherRoyal Society of Chemistry
dc.title.enSubstantial exchange coupling for {Mo-NCS-M} combination: illustration for 1-D [{Mo(NCS)6}{NiL}2(NCS)]n.
dc.typeArticle de revue
dc.identifier.doi10.1039/c0cc02498h
dc.subject.halChimie/Matériaux
bordeaux.journalChemical Communications
bordeaux.page7519-7521
bordeaux.volume46
bordeaux.issue40
bordeaux.peerReviewedoui
hal.identifierhal-00530396
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00530396v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Chemical%20Communications&rft.date=2010-10-28&rft.volume=46&rft.issue=40&rft.spage=7519-7521&rft.epage=7519-7521&rft.eissn=1359-7345&rft.issn=1359-7345&rft.au=MOUSAVI,%20Maliheh&B%C3%89REAU,%20Virginie&DESPLANCHES,%20C%C3%A9dric&GUYARD-DUHAYON,%20Carine&SUTTER,%20Jean-Pascal&rft.genre=article


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