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Substantial exchange coupling for {Mo-NCS-M} combination: illustration for 1-D [{Mo(NCS)6}{NiL}2(NCS)]n.
hal.structure.identifier | Laboratoire de chimie de coordination [LCC] | |
dc.contributor.author | MOUSAVI, Maliheh | |
hal.structure.identifier | Laboratoire de chimie de coordination [LCC] | |
dc.contributor.author | BÉREAU, Virginie | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | DESPLANCHES, Cédric | |
hal.structure.identifier | Laboratoire de chimie de coordination [LCC] | |
dc.contributor.author | GUYARD-DUHAYON, Carine | |
hal.structure.identifier | Laboratoire de chimie de coordination [LCC] | |
dc.contributor.author | SUTTER, Jean-Pascal | |
dc.date.issued | 2010-10-28 | |
dc.identifier.issn | 1359-7345 | |
dc.description.abstractEn | An antiferromagnetic interaction of J = -51 cm(-1) has been obtained in a NCS-bridged {Mo(III)-Ni} compound (i.e. [{Mo(NCS)(6)}{NiL}(2)(NCS)](n)), a value twice as large as for the homologous {Cr(III)-Ni} derivative. The DFT calculated spin distribution on {Mo(NCS)(6)}(3-) reveals noticeable spin on the S atoms. | |
dc.language.iso | en | |
dc.publisher | Royal Society of Chemistry | |
dc.title.en | Substantial exchange coupling for {Mo-NCS-M} combination: illustration for 1-D [{Mo(NCS)6}{NiL}2(NCS)]n. | |
dc.type | Article de revue | |
dc.identifier.doi | 10.1039/c0cc02498h | |
dc.subject.hal | Chimie/Matériaux | |
bordeaux.journal | Chemical Communications | |
bordeaux.page | 7519-7521 | |
bordeaux.volume | 46 | |
bordeaux.issue | 40 | |
bordeaux.peerReviewed | oui | |
hal.identifier | hal-00530396 | |
hal.version | 1 | |
hal.popular | non | |
hal.audience | Internationale | |
hal.origin.link | https://hal.archives-ouvertes.fr//hal-00530396v1 | |
bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Chemical%20Communications&rft.date=2010-10-28&rft.volume=46&rft.issue=40&rft.spage=7519-7521&rft.epage=7519-7521&rft.eissn=1359-7345&rft.issn=1359-7345&rft.au=MOUSAVI,%20Maliheh&B%C3%89REAU,%20Virginie&DESPLANCHES,%20C%C3%A9dric&GUYARD-DUHAYON,%20Carine&SUTTER,%20Jean-Pascal&rft.genre=article |
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