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hal.structure.identifierMoscow State University
dc.contributor.authorPRESNIAKOV, Igor A.
hal.structure.identifierMoscow State University
dc.contributor.authorRUSAKOV, Viyacheslav S.
hal.structure.identifierMoscow State University
dc.contributor.authorSOBOLEV, Alexey V.
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorDEMAZEAU, Gérard
hal.structure.identifierMoscow State University
dc.contributor.authorMATSNEV, M. E.
hal.structure.identifierMoscow State University
dc.contributor.authorGUBAIDULINA, Tatyana V.
hal.structure.identifierMoscow State University
dc.contributor.authorBARANOV, Alexey
dc.date.issued2010
dc.identifier.issn1062-8738
dc.description.abstractEnA comparative study of the electronic state of <sup>57</sup>Fe probe atoms in nickelates and cuprates La<i>M</i> <sub>0.99</sub> <sup>57</sup>Fe<sub>0.01</sub>O<sub>3</sub> and LaSr<i>M</i> <sub>0.99</sub> <sup>57</sup>Fe<sub>0.01</sub>O<sub>4</sub> (<i>M</i> = Ni, Cu) was performed by Mössbauer spectroscopy. It was shown that the valence states of the probe atoms in these matrices differ considerably. The iron atoms in both nickelates are in one of their conventional valence states (Fe<sup>3+</sup>), while the hyperfine interaction parameters in the cuprates correspond to iron atoms in a formal oxidation state of +4. The differences observed in the valence states of the probe <sup>57</sup>Fe atoms are due to the different electronic configurations of Ni and Cu atoms in the oxides under consideration.
dc.language.isoen
dc.publisherSpringer Verlag/Russian Academy of Sciences (RAS)
dc.typeArticle de revue
dc.identifier.doi10.3103/S1062873810030214
dc.subject.halChimie/Matériaux
bordeaux.journalBulletin of the Russian Academy of Sciences - Physics
bordeaux.page384-388
bordeaux.volume74
bordeaux.issue3
bordeaux.peerReviewedoui
hal.identifierhal-00551891
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00551891v1
bordeaux.COinSctx_ver=Z39.88-2004&amp;rft_val_fmt=info:ofi/fmt:kev:mtx:journal&amp;rft.jtitle=Bulletin%20of%20the%20Russian%20Academy%20of%20Sciences%20-%20Physics&amp;rft.date=2010&amp;rft.volume=74&amp;rft.issue=3&amp;rft.spage=384-388&amp;rft.epage=384-388&amp;rft.eissn=1062-8738&amp;rft.issn=1062-8738&amp;rft.au=PRESNIAKOV,%20Igor%20A.&amp;RUSAKOV,%20Viyacheslav%20S.&amp;SOBOLEV,%20Alexey%20V.&amp;DEMAZEAU,%20G%C3%A9rard&amp;MATSNEV,%20M.%20E.&amp;rft.genre=article


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