6/7Li NMR study of the Li1-zNi1+zO2 phases
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | CHAZEL, Cédric | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | MÉNÉTRIER, Michel | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | CROGUENNEC, Laurence | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | DELMAS, Claude | |
| dc.date.issued | 2005 | |
| dc.identifier.issn | 0749-1581 | |
| dc.description.abstractEn | A series of Li1-zNi1+zO2 materials have been synthesised by the coprecipitation route. An X-ray diffraction study was carried out on these materials using the Rietveld method to determine the departure from the ideal stoichiometry z, which ranges from 0 to 0.138. The actual Li/Ni ratio was also checked by chemical analyses using inductively coupled plasma (ICP) for each sample. The stoichiometric sample (z 0) was obtained using a 15% Li excess. 6/7Li NMR results from LiNiO2 (z 0) show that the asymmetric shape of the NMR signal is due to anisotropy. Calculations give evidence that the paramagnetic dipolar interaction from the electron spins carried by Ni is anisotropic but does not completely explain the experimental anisotropy. 6Li MAS NMR (magic angle spinning NMR) experiments and temperature standardisation NMR measurements unambiguously assign the isotropic position at +726 ppm. The static-echo NMR spectra of the non-stoichiometric Li1-zNi1+zO2 phases also exhibit an asymmetric shape whose width increases with the departure from the ideal stoichiometry z. 6/7Li static and MAS NMR show that the 2zNi2+ ions thus formed modify the dipolar interaction within the materials and also affect the Fermi contact interaction, since a distribution of Li environments is observed using 6Li NMR for non-stoichiometric samples | |
| dc.language.iso | en | |
| dc.publisher | Wiley | |
| dc.subject.en | NMR | |
| dc.subject.en | 6Li | |
| dc.subject.en | 7Li | |
| dc.subject.en | Isotropic signal | |
| dc.subject.en | Dipolar interaction anisotropy | |
| dc.subject.en | Lithium-ion battery | |
| dc.subject.en | Lithium nickelate | |
| dc.subject.en | Coprecipitation route | |
| dc.subject.en | X-ray diffraction | |
| dc.title.en | 6/7Li NMR study of the Li1-zNi1+zO2 phases | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1002/mrc.1639 | |
| dc.subject.hal | Chimie/Matériaux | |
| bordeaux.journal | Magnetic Resonance in Chemistry | |
| bordeaux.page | p. 849-857 | |
| bordeaux.volume | vol. 43, n° 10 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00019046 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Non spécifiée | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00019046v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Magnetic%20Resonance%20in%20Chemistry&rft.date=2005&rft.volume=vol.%2043,%20n%C2%B0%2010&rft.spage=p.%20849-857&rft.epage=p.%20849-857&rft.eissn=0749-1581&rft.issn=0749-1581&rft.au=CHAZEL,%20C%C3%A9dric&M%C3%89N%C3%89TRIER,%20Michel&CROGUENNEC,%20Laurence&DELMAS,%20Claude&rft.genre=article |
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