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Photoswitching of the antiferromagnetic coupling in an oxamato-based dicopper(ii) anthracenophane.

hal.structure.identifierInstituto de Ciencia Molecular [ICMol]
dc.contributor.authorCASTELLANO, María
hal.structure.identifierInstituto de Ciencia Molecular [ICMol]
dc.contributor.authorFERRANDO-SORIA, Jesús
hal.structure.identifierInstituto de Ciencia Molecular [ICMol]
dc.contributor.authorPARDO, Emilio
hal.structure.identifierInstituto de Ciencia Molecular [ICMol]
dc.contributor.authorJULVE, Miguel
hal.structure.identifierInstituto de Ciencia Molecular [ICMol]
dc.contributor.authorLLORET, Francesc
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorMATHONIÈRE, Corine
hal.structure.identifierLaboratorio de Rayos X y Materiales Moleculares
dc.contributor.authorPASÁN, Jorge
hal.structure.identifierLaboratorio de Rayos X y Materiales Moleculares
dc.contributor.authorRUIZ-PÉREZ, Catalina
hal.structure.identifierLaboratorio de Rayos X y Materiales Moleculares
hal.structure.identifierInstitut Laue-Langevin [ILL]
hal.structure.identifierInstituto de Ciencia de Materiales de Aragón [Saragoza, España] [ICMA-CSIC]
dc.contributor.authorCAÑADILLAS-DELGADO, Laura
hal.structure.identifierInstituto de Ciencia Molecular [ICMol]
hal.structure.identifierFundació General de la Universitat de València [FGUV]
dc.contributor.authorRUIZ-GARCÍA, Rafael
hal.structure.identifierInstituto de Ciencia Molecular [ICMol]
hal.structure.identifierFundació General de la Universitat de València [FGUV]
dc.contributor.authorCANO, Joan
dc.date.issued2011
dc.identifier.issn1359-7345
dc.description.abstractEnThermally reversible photomagnetic (ON/OFF) switching behavior has been observed in a dinuclear oxamatocopper(ii) anthracenophane upon UV light irradiation and heating; the two Cu(II) ions (S(Cu) = 1/2) that are antiferromagnetically coupled in the dicopper(ii) metallacyclic precursor (ON state) become uncoupled in the corresponding [4+4] photocycloaddition product (OFF state), as substantiated from both experimental and theoretical studies.
dc.language.isoen
dc.publisherRoyal Society of Chemistry
dc.title.enPhotoswitching of the antiferromagnetic coupling in an oxamato-based dicopper(ii) anthracenophane.
dc.typeArticle de revue
dc.identifier.doi10.1039/c1cc15087a
dc.subject.halChimie/Matériaux
bordeaux.journalChemical Communications
bordeaux.page11035-11037
bordeaux.volume47
bordeaux.issue39
bordeaux.peerReviewedoui
hal.identifierhal-00634275
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00634275v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Chemical%20Communications&rft.date=2011&rft.volume=47&rft.issue=39&rft.spage=11035-11037&rft.epage=11035-11037&rft.eissn=1359-7345&rft.issn=1359-7345&rft.au=CASTELLANO,%20Mar%C3%ADa&FERRANDO-SORIA,%20Jes%C3%BAs&PARDO,%20Emilio&JULVE,%20Miguel&LLORET,%20Francesc&rft.genre=article


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