Photoswitching of the antiferromagnetic coupling in an oxamato-based dicopper(ii) anthracenophane.
CAÑADILLAS-DELGADO, Laura
Laboratorio de Rayos X y Materiales Moleculares
Institut Laue-Langevin [ILL]
Instituto de Ciencia de Materiales de Aragón [Saragoza, España] [ICMA-CSIC]
Laboratorio de Rayos X y Materiales Moleculares
Institut Laue-Langevin [ILL]
Instituto de Ciencia de Materiales de Aragón [Saragoza, España] [ICMA-CSIC]
RUIZ-GARCÍA, Rafael
Instituto de Ciencia Molecular [ICMol]
Fundació General de la Universitat de València [FGUV]
Instituto de Ciencia Molecular [ICMol]
Fundació General de la Universitat de València [FGUV]
CANO, Joan
Instituto de Ciencia Molecular [ICMol]
Fundació General de la Universitat de València [FGUV]
< Réduire
Instituto de Ciencia Molecular [ICMol]
Fundació General de la Universitat de València [FGUV]
Langue
en
Article de revue
Ce document a été publié dans
Chemical Communications. 2011, vol. 47, n° 39, p. 11035-11037
Royal Society of Chemistry
Résumé en anglais
Thermally reversible photomagnetic (ON/OFF) switching behavior has been observed in a dinuclear oxamatocopper(ii) anthracenophane upon UV light irradiation and heating; the two Cu(II) ions (S(Cu) = 1/2) that are ...Lire la suite >
Thermally reversible photomagnetic (ON/OFF) switching behavior has been observed in a dinuclear oxamatocopper(ii) anthracenophane upon UV light irradiation and heating; the two Cu(II) ions (S(Cu) = 1/2) that are antiferromagnetically coupled in the dicopper(ii) metallacyclic precursor (ON state) become uncoupled in the corresponding [4+4] photocycloaddition product (OFF state), as substantiated from both experimental and theoretical studies.< Réduire
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