Construction of tube- and ladderlike copper(II). Coordination polymers based on the nicotinato tecton
| hal.structure.identifier | Inorganic Chemistry Laboratory-Faculty of Chemistry | |
| dc.contributor.author | MADALAN, Augustin M. | |
| hal.structure.identifier | Inorganic Chemistry Laboratory-Faculty of Chemistry | |
| dc.contributor.author | PARASCHIV, Carmen | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | SUTTER, Jean-Pascal | |
| hal.structure.identifier | Fakultät für Chemie [Universität Bielefeld] | |
| dc.contributor.author | SCHMIDTMANN, Marc | |
| hal.structure.identifier | Fakultät für Chemie [Universität Bielefeld] | |
| dc.contributor.author | MÜLLER, Achim | |
| hal.structure.identifier | Inorganic Chemistry Laboratory-Faculty of Chemistry | |
| dc.contributor.author | ANDRUH, Marius | |
| dc.date.issued | 2005 | |
| dc.identifier.issn | 1528-7483 | |
| dc.description.abstractEn | Three 1-D copper(II) coordination polymers have been obtained by using the nicotinato anion (NA-) as a bridge, and 2,2'-bipyridine or dicyanamide (dca) as coligands: Cu2(bipy)2(NA)2](ClO4)2·H2O 1, Cu2(Me2bipy)2(NA)2](ClO4)2 2, Cu3(NA)4(dca)2(H2O)8]·2H2O 3 (bipy = 2,2'-bipyridine; Me2bipy = 4,4'-dimethyl-2,2'-bipyridine, dca = dicyanamide anion). The metal-ligand association in compounds 1 and 2 is very similar and generates tubelike coordination polymers, which are constructed from pairs of copper atoms connected through two carboxylato groups from two NA- ligands. Each pyridyl moiety from the NA- ligand coordinates at the apical position of the copper ions from another pair, resulting in chains running along the crystallographic c axis. The structure of 3 consists of infinite ladderlike chains: the rungs are formed by trinuclear [Cu3] moieties, with the copper(II) ions connected through NA- bridges, the ladder sides being constructed from dca- bridging ligands. The cryomagnetic investigation of the three compounds reveals weak antiferromagnetic interactions mediated by the nicotinato ligand, 1: J = -7.3 cm-1, 2: -15.3 cm-1, 3: -0.58 cm-1 | |
| dc.language.iso | en | |
| dc.publisher | American Chemical Society | |
| dc.subject.en | Magnetic properties | |
| dc.subject.en | Crystal structures | |
| dc.subject.en | Complexes | |
| dc.subject.en | Networks | |
| dc.title.en | Construction of tube- and ladderlike copper(II). Coordination polymers based on the nicotinato tecton | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1021/cg049797m | |
| dc.subject.hal | Chimie/Matériaux | |
| bordeaux.journal | Crystal Growth & Design | |
| bordeaux.page | 707-711 | |
| bordeaux.volume | 5 | |
| bordeaux.issue | 2 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00022194 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00022194v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Crystal%20Growth%20&%20Design&rft.date=2005&rft.volume=5&rft.issue=2&rft.spage=707-711&rft.epage=707-711&rft.eissn=1528-7483&rft.issn=1528-7483&rft.au=MADALAN,%20Augustin%20M.&PARASCHIV,%20Carmen&SUTTER,%20Jean-Pascal&SCHMIDTMANN,%20Marc&M%C3%9CLLER,%20Achim&rft.genre=article |
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