Afficher la notice abrégée

hal.structure.identifierDepartment of Chemistry
dc.contributor.authorSHEPHERD, Helena
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorROSA, Patrick
hal.structure.identifierSchool of Chemistry [Cardiff]
dc.contributor.authorFALLIS, Ian A.
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorGUIONNEAU, Philippe
hal.structure.identifierDepartment of Chemistry
dc.contributor.authorHOWARD, Judith A. K.
hal.structure.identifierDepartment of Chemistry
dc.contributor.authorGOETA, Andrés E.
dc.date.issued2012
dc.identifier.issn0022-3697
dc.description.abstractEnVariable temperature single crystal X-ray diffraction and SQUID magnetometry experiments have revealed a gradual spin transition in [FeII(L)](ClO4)2 (where L=1,4,7-tris(2-aminophenyl)-1,4,7-triazacyclononane), centred around room temperature. The gradual nature of the spin transition has been attributed to the lack of significant intermolecular interactions between iron centres and the propensity of the counter ions to accommodate the internal strain in the crystal caused by spin crossover.
dc.language.isoen
dc.publisherElsevier
dc.subject.enOrganometallic compounds
dc.subject.enX-ray diffraction
dc.subject.enMagnetic properties
dc.subject.enCrystal structure
dc.title.enStructural origin of the gradual spin transition in a mononuclear iron(II) complex
dc.typeArticle de revue
dc.identifier.doi10.1016/j.jpcs.2011.11.003
dc.subject.halChimie/Matériaux
bordeaux.journalJournal of Physics and Chemistry of Solids
bordeaux.page193-197
bordeaux.volume73
bordeaux.issue2
bordeaux.peerReviewedoui
hal.identifierhal-00653775
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00653775v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Journal%20of%20Physics%20and%20Chemistry%20of%20Solids&rft.date=2012&rft.volume=73&rft.issue=2&rft.spage=193-197&rft.epage=193-197&rft.eissn=0022-3697&rft.issn=0022-3697&rft.au=SHEPHERD,%20Helena&ROSA,%20Patrick&FALLIS,%20Ian%20A.&GUIONNEAU,%20Philippe&HOWARD,%20Judith%20A.%20K.&rft.genre=article


Fichier(s) constituant ce document

FichiersTailleFormatVue

Il n'y a pas de fichiers associés à ce document.

Ce document figure dans la(les) collection(s) suivante(s)

Afficher la notice abrégée