Photomagnetic studies on spin-crossover solid solutions containing two different metal complexes, [Fe(1-bpp)(2)](x)[M(terpy)(2)](1-x)[BF(4)](2) (M = Ru or Co).
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | CHASTANET, Guillaume | |
| hal.structure.identifier | School of Chemistry [Leeds] | |
| dc.contributor.author | TOVEE, Clare A. | |
| hal.structure.identifier | School of Chemistry [Leeds] | |
| dc.contributor.author | HYETT, Geoffrey | |
| hal.structure.identifier | School of Chemistry [Leeds] | |
| dc.contributor.author | HALCROW, Malcolm A. | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | LÉTARD, Jean-François | |
| dc.date.issued | 2012 | |
| dc.identifier.issn | 1477-9226 | |
| dc.description.abstractEn | The photomagnetic properties of two series of spin-crossover solid solutions, [Fe(1-bpp)(2)](x)[Ru(terpy)(2)](1-x)(BF(4))(2) and [Fe(1-bpp)(2)](x)[Co(terpy)(2)](1-x)(BF(4))(2) (1-bpp = 2,6-bis[pyrazol-1-yl]pyridine), have been investigated. For all the materials, the evolution of the T(LIESST) value, the high-spin → low-spin relaxation parameters and the LITH loops were thoroughly studied. Interestingly in the Fe : Co series, along the photo-excitation, cobalt ions are concomitantly converted from low-spin to high-spin states with the iron centres, and also fully relax after light excitation. | |
| dc.language.iso | en | |
| dc.publisher | Royal Society of Chemistry | |
| dc.subject.en | Photomagnetic properties | |
| dc.subject.en | Spin-crossover | |
| dc.subject.en | Solid solutions | |
| dc.subject.en | LIESST | |
| dc.title.en | Photomagnetic studies on spin-crossover solid solutions containing two different metal complexes, [Fe(1-bpp)(2)](x)[M(terpy)(2)](1-x)[BF(4)](2) (M = Ru or Co). | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1039/c2dt12122k | |
| dc.subject.hal | Chimie/Matériaux | |
| bordeaux.journal | Dalton Transactions | |
| bordeaux.page | 4896-4902 | |
| bordeaux.volume | 41 | |
| bordeaux.issue | 16 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00684070 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00684070v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Dalton%20Transactions&rft.date=2012&rft.volume=41&rft.issue=16&rft.spage=4896-4902&rft.epage=4896-4902&rft.eissn=1477-9226&rft.issn=1477-9226&rft.au=CHASTANET,%20Guillaume&TOVEE,%20Clare%20A.&HYETT,%20Geoffrey&HALCROW,%20Malcolm%20A.&L%C3%89TARD,%20Jean-Fran%C3%A7ois&rft.genre=article |
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