A new strontium lithium titanium oxide, SrLi2Ti6O14 : crystal growth and structure determination
| hal.structure.identifier | Institute of General and Inorganic Chemistry | |
| dc.contributor.author | KOSEVA, Iovka | |
| hal.structure.identifier | Institute of General and Inorganic Chemistry | |
| dc.contributor.author | PESHEV, Pavel | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | PECHEV, Stanislav | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | GRAVEREAU, Pierre | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | CHAMINADE, Jean-Pierre | |
| dc.date.issued | 2014 | |
| dc.identifier.issn | 0932-0776 | |
| dc.description.abstractEn | A new strontium lithium titanate with composition SrLi2Ti6O14 has been discovered in the ternary system SrO - Li2O - TiO2. Single crystals of this compound have been grown by the flux method. The structure of SrLi2Ti6O14 has been solved using X-ray data (Mo-Kÿ radiation, orthorhombic, space group Cmca, Z = 8, with a = 16.570(5), b = 11.150(2), c = 11.458(2) A˚ , R1 = 0.039 (wR2 = 0.087)). The crystal structure is built by edge and corner sharing TiO6 octahedra which form layers parallel to the (100) plane. Consecutive layers [deduced from a mirror plane parallel to (100)] are linked by common corners in the a direction. Lithium atoms in tetrahedral coordination occupy vacancies of the framework of titanium octahedra, while strontium atoms lie in 11-coordinated sites between two successive layers. | |
| dc.language.iso | en | |
| dc.publisher | Verlag der Zeitschrift Fuer Naturforschung | |
| dc.subject.en | Strontium Lithium Titanate | |
| dc.subject.en | Flux Crystal Growth | |
| dc.subject.en | Structure Determination | |
| dc.title.en | A new strontium lithium titanium oxide, SrLi2Ti6O14 : crystal growth and structure determination | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1515/znb-2002-0507 | |
| dc.subject.hal | Chimie/Matériaux | |
| bordeaux.journal | Zeitschrift fur Naturforschung B | |
| bordeaux.page | 512-518 | |
| bordeaux.volume | 57 | |
| bordeaux.issue | 5 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00717774 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00717774v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Zeitschrift%20fur%20Naturforschung%20B&rft.date=2014&rft.volume=57&rft.issue=5&rft.spage=512-518&rft.epage=512-518&rft.eissn=0932-0776&rft.issn=0932-0776&rft.au=KOSEVA,%20Iovka&PESHEV,%20Pavel&PECHEV,%20Stanislav&GRAVEREAU,%20Pierre&CHAMINADE,%20Jean-Pierre&rft.genre=article |
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