A new strontium lithium titanium oxide, SrLi2Ti6O14 : crystal growth and structure determination
Language
en
Article de revue
This item was published in
Zeitschrift fur Naturforschung B. 2014, vol. 57, n° 5, p. 512-518
Verlag der Zeitschrift Fuer Naturforschung
English Abstract
A new strontium lithium titanate with composition SrLi2Ti6O14 has been discovered in the ternary system SrO - Li2O - TiO2. Single crystals of this compound have been grown by the flux method. The structure of SrLi2Ti6O14 ...Read more >
A new strontium lithium titanate with composition SrLi2Ti6O14 has been discovered in the ternary system SrO - Li2O - TiO2. Single crystals of this compound have been grown by the flux method. The structure of SrLi2Ti6O14 has been solved using X-ray data (Mo-Kÿ radiation, orthorhombic, space group Cmca, Z = 8, with a = 16.570(5), b = 11.150(2), c = 11.458(2) A˚ , R1 = 0.039 (wR2 = 0.087)). The crystal structure is built by edge and corner sharing TiO6 octahedra which form layers parallel to the (100) plane. Consecutive layers [deduced from a mirror plane parallel to (100)] are linked by common corners in the a direction. Lithium atoms in tetrahedral coordination occupy vacancies of the framework of titanium octahedra, while strontium atoms lie in 11-coordinated sites between two successive layers.Read less <
English Keywords
Strontium Lithium Titanate
Flux Crystal Growth
Structure Determination
Origin
Hal imported