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A family of discrete magnetaically switchable nanoballs

hal.structure.identifierSchool of Chemistry
dc.contributor.authorDURISKA MARTIN, B.
hal.structure.identifierSchool of Chemistry
dc.contributor.authorNEVILLE, Suzanne M.
hal.structure.identifierSchool of Chemistry
dc.contributor.authorMOUBARAKI, Boujemaa
hal.structure.identifierSchool of Chemistry
dc.contributor.authorMURRAY, Keith S.
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
hal.structure.identifierLaboratoire de Chimie et Physique des Matériaux [LCPM]
dc.contributor.authorBALDÉ, Cherif
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorLÉTARD, Jean-François
hal.structure.identifierSchool of Chemistry
dc.contributor.authorKEPERT, Cameron J.
hal.structure.identifierSchool of Chemistry
dc.contributor.authorBATTEN, Stuart R.
dc.date.issued2012
dc.identifier.issn2192-6506
dc.description.abstractEnThe thermal and light-induced magnetic properties of a family of discrete magnetically switchable "nanoball" species (3 nm in diameter) is reported. The self-assembly of these materials is accomplished by the use of the metallo building block, [Cu([Tp4-py])(NCCH3)] ([Tp4-py]=tris-[3-(4'-pyridyl)pyrazol-1-yl]hydroborate), combined with a [Fe(NCX)2] (X=S, Se and BH3) species. We previously showed that the thiocyanate analogue (Fe(NCS)-nano) undergoes a thermal and light-induced spin crossover (SCO)--the largest such discrete SCO material reported. Now included in this family are the Se and BH3 analogues, Fe(NCSe)-nano and Fe(NCBH3)-nano, which show increased thermal transition temperatures (T1/2=124 K, 162 and 173 K). This variation in transition temperature over the series S
dc.language.isoen
dc.publisherWiley
dc.title.enA family of discrete magnetaically switchable nanoballs
dc.typeArticle de revue
dc.identifier.doi10.1002/cplu.201200123
dc.subject.halChimie/Matériaux
bordeaux.journalChemPlusChem
bordeaux.page616-623
bordeaux.volume77
bordeaux.issue8
bordeaux.peerReviewedoui
hal.identifierhal-00747368
hal.version1
hal.popularnon
hal.audienceInternationale
dc.subject.itDiscrete
dc.subject.itIron
dc.subject.itLIESST
dc.subject.itSpin crossover
dc.subject.itSupramolecules
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00747368v1
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