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Synthesis and magnetic properties of the ternary germanide TbScGe
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | TENCÉ, Sophie | |
hal.structure.identifier | Matériaux, Rayonnements, Structure [NEEL - MRS] | |
dc.contributor.author | ISNARD, Olivier | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | GAUDIN, Etienne | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | CHEVALIER, Bernard | |
dc.date.issued | 2013 | |
dc.identifier.issn | 0925-8388 | |
dc.description.abstractEn | TbScGe is obtained as pure phase after melting of the constituents followed by an annealing at 1173 K. Contrary to what was suggested previously, this ternary germanide does not present a high temperature form with the hexagonal Ti5Ga4-type structure after melting and quenching; the as quenched sample is a mixture based on the two solid solutions (Tb1−xScx)5Ge3 and Tb1−xScx. TbScGe adopts the tetragonal CeScSi-type structure with a = 4.219 and c = 15.452 Å as unit cell parameters. Its investigation by magnetization and specific heat measurements reveals a ferromagnetic behavior below TC = 250 K inducing a moderate magnetocaloric effect; for a magnetic field change of 2 T, the magnetic entropy change ΔSm is equal to −1.6 J K−1 kg−1 which corresponds to an adiabatic temperature change ΔTad of 1.25 K. | |
dc.language.iso | en | |
dc.publisher | Elsevier | |
dc.subject.en | Structural properties | |
dc.subject.en | Synthesis | |
dc.subject.en | Ternary germanide | |
dc.subject.en | Ferromagnetism | |
dc.subject.en | Magnetocaloric properties | |
dc.title.en | Synthesis and magnetic properties of the ternary germanide TbScGe | |
dc.type | Article de revue | |
dc.identifier.doi | 10.1016/j.jallcom.2013.02.002 | |
dc.subject.hal | Chimie/Matériaux | |
bordeaux.journal | Journal of Alloys and Compounds | |
bordeaux.page | 195-199 | |
bordeaux.volume | 560 | |
bordeaux.peerReviewed | oui | |
hal.identifier | hal-00797634 | |
hal.version | 1 | |
hal.popular | non | |
hal.audience | Internationale | |
hal.origin.link | https://hal.archives-ouvertes.fr//hal-00797634v1 | |
bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Journal%20of%20Alloys%20and%20Compounds&rft.date=2013&rft.volume=560&rft.spage=195-199&rft.epage=195-199&rft.eissn=0925-8388&rft.issn=0925-8388&rft.au=TENC%C3%89,%20Sophie&ISNARD,%20Olivier&GAUDIN,%20Etienne&CHEVALIER,%20Bernard&rft.genre=article |
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